The influence of metal stearates on the water sensitivity of modern oil paints

作者: Donatella Banti , Aviva Burnstock , Ilaria Bonaduce , Jacopo La Nasa , Judith Lee

DOI: 10.1007/978-3-030-19254-9_35

关键词:

摘要: The influence of free metal stearates, other soaps and fatty acids on the water sensitivity modern oil paint swatches from three brands artists’ manufactured tube paints was investigated. produced in 2006 tested for 2008 were re-tested, changes recorded. Swatches with a range to those that exhibited visible surface deterioration selected chemical optical characterisation. This included novel method sample preparation gas chromatography coupled mass spectrometry (GC/MS) quantitative analysis dicarboxylic related soaps. Results suggested proportion does not relate surface. It is therefore likely polymeric/ionomeric network plays an important role sensitivity. showed acid efflorescence linked high levels (FFA) swatch extent proportional results found GC/MS analyses.

参考文章(10)
Francesca Caterina Izzo, Klaas Jan van den Berg, Henk van Keulen, Barbara Ferriani, Elisabetta Zendri, Modern Oil Paints – Formulations, Organic Additives and Degradation: Some Case Studies Issues on Contemporary Oil paints. pp. 75- 104 ,(2014) , 10.1007/978-3-319-10100-2_5
Jacopo La Nasa, Elisa Ghelardi, Ilaria Degano, Francesca Modugno, Maria Perla Colombini, Core shell stationary phases for a novel separation of triglycerides in plant oils by high performance liquid chromatography with electrospray-quadrupole-time of flight mass spectrometer. Journal of Chromatography A. ,vol. 1308, pp. 114- 124 ,(2013) , 10.1016/J.CHROMA.2013.08.015
Joen J. Hermans, Katrien Keune, Annelies van Loon, Piet D. Iedema, An infrared spectroscopic study of the nature of zinc carboxylates in oil paintings Journal of Analytical Atomic Spectrometry. ,vol. 30, pp. 1600- 1608 ,(2015) , 10.1039/C5JA00120J
Jorrit D.J. Van Den Berg, Klaas Jan Van Den Berg, Jaap J. Boon, Chemical changes in curing and ageing oil paints James & James. pp. 248- 253 ,(1999)
Jorrit Dirk Jan van den Berg, Analytical chemical studies on traditional linseed oil paints MOLART. ,(2002)
Jacopo La Nasa, Francesca Modugno, Matteo Aloisi, Anna Lluveras-Tenorio, Ilaria Bonaduce, Development of a GC/MS method for the qualitative and quantitative analysis of mixtures of free fatty acids and metal soaps in paint samples. Analytica Chimica Acta. ,vol. 1001, pp. 51- 58 ,(2018) , 10.1016/J.ACA.2017.11.017
Donatella Banti, Jacopo La Nasa, Anna Lluveras Tenorio, Francesca Modugno, Klaas Jan van den Berg, Judith Lee, Bronwyn Ormsby, Aviva Burnstock, Ilaria Bonaduce, A molecular study of modern oil paintings: investigating the role of dicarboxylic acids in the water sensitivity of modern oil paints RSC Advances. ,vol. 8, pp. 6001- 6012 ,(2018) , 10.1039/C7RA13364B
Judith Lee, Ilaria Bonaduce, Francesca Modugno, Jacopo La Nasa, Bronwyn Ormsby, Klaas Jan van den Berg, Scientific investigation into the water sensitivity of twentieth century oil paints Microchemical Journal. ,vol. 138, pp. 282- 295 ,(2018) , 10.1016/J.MICROC.2018.01.017
Jacopo La Nasa, Anna Lluveras-Tenorio, Francesca Modugno, Ilaria Bonaduce, Two-step analytical procedure for the characterization and quantification of metal soaps and resinates in paint samples Heritage Science. ,vol. 6, pp. 1- 10 ,(2018) , 10.1186/S40494-018-0222-1
Francesca Modugno, Fabiana Di Gianvincenzo, Ilaria Degano, Inez Dorothé van der Werf, Ilaria Bonaduce, Klaas Jan van den Berg, On the influence of relative humidity on the oxidation and hydrolysis of fresh and aged oil paints. Scientific Reports. ,vol. 9, pp. 1- 16 ,(2019) , 10.1038/S41598-019-41893-9