Preparation and characterization of highly c-axis-oriented Bi4Ti3O12 thin films

作者: Masaki Yamaguchi , Kensuke Kawanabe , Takao Nagatomo , Osamu Omoto

DOI: 10.1016/S0921-5107(96)01640-6

关键词:

摘要: Highly c-axis-oriented bismuth litanale (Bi4Ti3O12) thin films were prepared on (100)-oriented silicon wafers by rf planar magnetron sputtering using a target of Bi2TiO5 ceramic at low substrate temperature 600 °C. The with c-axis orientation up to 99%. obtained under high deposition rate approximately 1.1 μm h 1. Dielectric constant these dependence film thickness. This behavior was explained assuming low-dielectric-constant interface layer. Using this assumption, the dielectric Bi4Ti3O12 estimated be 140. value is similar that along in bulk form. A D E hysteresis characteristic has been observed room temperature. remanent polarisation and coercive field are 0.8 μC cm 2 20 kV respectively. From analysis refractive index, layer confirmed an oxidixed silicon, which formed before or during deposition.

参考文章(14)
Takashi Mihara, Hiroyuki Yoshimori, Hitoshi Watanabe, Carlos A. Paz de Araujo, Characteristics of Bismuth Layered SrBi2Ta2O9 Thin-Film Capacitors and Comparison with Pb(Zr, Ti)O3 Japanese Journal of Applied Physics. ,vol. 34, pp. 5233- 5239 ,(1995) , 10.1143/JJAP.34.5233
Kenji Iijima, Yoshihiro Tomita, Ryoichi Takayama, Ichiro Ueda, Preparation ofc‐axis oriented PbTiO3thin films and their crystallographic, dielectric, and pyroelectric properties Journal of Applied Physics. ,vol. 60, pp. 361- 367 ,(1986) , 10.1063/1.337654
J. J. Lee, C. L. Thio, S. B. Desu, Electrode contacts on ferroelectric Pb(ZrxTi1−x)O3 and SrBi2Ta2O9 thin films and their influence on fatigue properties Journal of Applied Physics. ,vol. 78, pp. 5073- 5078 ,(1995) , 10.1063/1.359737
M. DrDomenico, S. H. Wemple, Oxygen‐Octahedra Ferroelectrics. I. Theory of Electro‐optical and Nonlinear optical Effects Journal of Applied Physics. ,vol. 40, pp. 720- 734 ,(1969) , 10.1063/1.1657458
Takeshi Okamura, Masatoshi Adachi, Tadashi Shiosaki, Akira Kawabata, Epitaxial Growth and Electrical Properties of Ferroelectric Pb(Zr0.9Ti0.1)O3Films by Reactive Sputtering Japanese Journal of Applied Physics. ,vol. 30, pp. 1034- 1037 ,(1991) , 10.1143/JJAP.30.1034
Masaki Yamaguchi, Takao Nagatomo, Osamu Omoto, Physical properties of Bi4Ti3O12 films grown on Si(100) wafers Japanese Journal of Applied Physics. ,vol. 34, pp. 5116- 5119 ,(1995) , 10.1143/JJAP.34.5116
Tadashi Takenaka, Koichiro Sakata, Grain Orientation and Electrical Properties of Hot-Forged Bi4Ti3O12 Ceramics Japanese Journal of Applied Physics. ,vol. 19, pp. 31- 39 ,(1980) , 10.1143/JJAP.19.31
Isaku Kanno, Shigenori Hayashi, Takeshi Kamada, Masatoshi Kitagawa, Takashi Hirao, Characterization of Pb(Zr, Ti)O3 Thin Films Prepared by Multi-Ion-Beam Sputtering Japanese Journal of Applied Physics. ,vol. 33, pp. 574- 577 ,(1994) , 10.1143/JJAP.33.574
J. F. Dorrian, R. E. Newnham, D. K. Smith, M. I. Kay, Crystal structure of Bi4Ti3O12 Ferroelectrics. ,vol. 3, pp. 17- 27 ,(1972) , 10.1080/00150197108237680