Lithium nitride (Li3N): standard enthalpy of formation by solution calorimetry
作者： P.A.G. O'Hare , Gerald K. Johnson
DOI: 10.1016/0021-9614(75)90075-0
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摘要: Abstract The enthalpies of reaction a carefully prepared and characterized specimen lithium nitride, Li 3 N, with H 2 O HCl(aq) were found to be −(581.62±1.42) kJ mol −1 [−(139.01±0.34) kcal th ] −(803.50±1.26) [−(192.04±0.30) ], respectively. Enthalpies solution LiCl NH 4 Cl also measured. Combination the measured results auxiliary thermochemical data from literature yielded values −(165.14±1.55) [−(39.47±0.37) −(164.77±1.51) [−(39.38±0.36) respectively, for standard enthalpy formation, ΔH f o (Li c, 298.15 K). A weighted mean value, −(164.93±1.09) [−(39.42±0.26) is recommended This result differs by about 8 previous determinations.
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B. Neumann, C. Kröger, H. Haebler, Die Bildungswärmen der Nitride. Die Azotierungswärmen von Lithium, Aluminium, Beryllium und Magnesium Zeitschrift für anorganische und allgemeine Chemie. ,vol. 204, pp. 81- 96 ,(1932) , 10.1002/ZAAC.19322040111
Cecil E Vanderzee, Delbert L King, Ingemar Wadsö, The enthalpy of ionization of aqueous ammonia The Journal of Chemical Thermodynamics. ,vol. 4, pp. 685- 689 ,(1972) , 10.1016/0021-9614(72)90040-7
Cecil E. Vanderzee, Margret Månsson, Ingemar Wadsö, Stig Sunner, Enthalpies of formation of mono- and diammonium succinates and of aqueous ammonia and ammonium ion The Journal of Chemical Thermodynamics. ,vol. 4, pp. 541- 550 ,(1972) , 10.1016/0021-9614(72)90076-6
William C. Gough, Bernard J. Eastlund, The Prospects of Fusion Power Scientific American. ,vol. 224, pp. 50- 64 ,(1971) , 10.1038/SCIENTIFICAMERICAN0271-50