A novel σ-linkage to dianchor dyes for efficient dyes sensitized solar cells: 3-methyl-1,1-cyclohexane
作者： Isolda Duerto , Marta García-Palacín , Daniel Barrios , Javier Garín , Jesús Orduna
DOI: 10.1016/J.DYEPIG.2019.107945
关键词:
摘要: Abstract We have synthesized two sensitizers based on the 3-methyl-1,1-cyclohexane, a novel σ-linkage to prepare dianchored dyes. These dyes are difunctionalized systems with aniline-donor (D), π-conjugated spacer (π) thiophene or bithiophene and cyanoacetic acid as acceptor anchoring group (A). The UV–vis absorption Differential Pulse Voltammetry been used study effect of both π-spacer. relevant increase molar extinction coefficient these has investigated by theoretical calculations. dye bearing results in broader higher well an adequate efficiency transfer charge from D A respect photovoltaic properties without co-adsorbent studied. derivatives present photocurrent density which better performance single derivative given rise value 7.8% is stable up 1000 h after device assembly.
sci-hub.se 参考文章(36)
Mao Liang, Jun Chen, Arylamine organic dyes for dye-sensitized solar cells Chemical Society Reviews. ,vol. 42, pp. 3453- 3488 ,(2013) , 10.1039/C3CS35372A
Ryan Yeh-Yung Lin, Feng-Ling Wu, Chia-Hao Chang, Hsien-Hsin Chou, Tzu-Man Chuang, Te-Chun Chu, Chih-Yu Hsu, Ping-Wei Chen, Kuo-Chuan Ho, Yih-Hsing Lo, Jiann T. Lin, Y-shaped metal-free D–π–(A)2 sensitizers for high-performance dye-sensitized solar cells Journal of Materials Chemistry. ,vol. 2, pp. 3092- 3101 ,(2014) , 10.1039/C3TA14404F
Raquel Andreu, Santiago Franco, Javier Garín, Judith Romero, Belén Villacampa, María Jesús Blesa, Jesús Orduna, None, Multichromophoric calix[4]arenes: Effect of interchromophore distances on linear and nonlinear optical properties ChemPhysChem. ,vol. 13, pp. 3204- 3209 ,(2012) , 10.1002/CPHC.201200203
Eva M. Barea, Ceylan Zafer, Burak Gultekin, Banu Aydin, Sermet Koyuncu, Siddik Icli, Francisco Fabregat Santiago, Juan Bisquert, Quantification of the Effects of Recombination and Injection in the Performance of Dye-Sensitized Solar Cells Based on N-Substituted Carbazole Dyes Journal of Physical Chemistry C. ,vol. 114, pp. 19840- 19848 ,(2010) , 10.1021/JP1055842
Mahalingavelar Paramasivam, Ramesh Kumar Chitumalla, Surya Prakash Singh, Ashraful Islam, Liyuan Han, V. Jayathirtha Rao, K. Bhanuprakash, Tuning the Photovoltaic Performance of Benzocarbazole-Based Sensitizers for Dye-Sensitized Solar Cells: A Joint Experimental and Theoretical Study of the Influence of π-Spacers Journal of Physical Chemistry C. ,vol. 119, pp. 17053- 17064 ,(2015) , 10.1021/ACS.JPCC.5B04629
Yu Kyung Eom, Sung Ho Kang, In Taek Choi, Youngjun Yoo, Jeongho Kim, Hwan Kyu Kim, Significant light absorption enhancement by a single heterocyclic unit change in the π-bridge moiety from thieno[3,2-b]benzothiophene to thieno[3,2-b]indole for high performance dye-sensitized and tandem solar cells Journal of Materials Chemistry. ,vol. 5, pp. 2297- 2308 ,(2017) , 10.1039/C6TA09836C
Meysam Pazoki, Ute B. Cappel, Erik M. J. Johansson, Anders Hagfeldt, Gerrit Boschloo, Characterization techniques for dye-sensitized solar cells Energy and Environmental Science. ,vol. 10, pp. 672- 709 ,(2017) , 10.1039/C6EE02732F
Liyuan Dong, Ran Chen, Qiang Weng, Zhongwei An, Xinbing Chen, Pei Chen, The effect of furan linkers on the properties of cyclic thiourea functionalized triphenylamine dye sensitizers Dyes and Pigments. ,vol. 139, pp. 772- 778 ,(2017) , 10.1016/J.DYEPIG.2017.01.014
Dhirendra Kumar, Ken-Tsung Wong, Organic dianchor dyes for dye-sensitized solar cells Materials Today Energy. ,vol. 5, pp. 243- 279 ,(2017) , 10.1016/J.MTENER.2017.05.007
I. Duerto, E. Colom, J.M. Andrés-Castán, S. Franco, J. Garín, J. Orduna, B. Villacampa, M.J. Blesa, DSSCs based on aniline derivatives functionalized with a tert-butyldimethylsilyl group and the effect of the π-spacer Dyes and Pigments. ,vol. 148, pp. 61- 71 ,(2018) , 10.1016/J.DYEPIG.2017.07.063