Chiral Discrimination using Chiral Ordering Agents

作者: Jacques Courtieu , Philippe Lesot , Abdelkrim Meddour , Denis Merlet , Christie Aroulanda

DOI: 10.1002/9780470034590.EMRSTM0078

关键词:

摘要: The sections in this article are 1 Introduction 2 History 3 Chiral Discrimination using Polypeptidic Lyotropic Liquid Crystals 4 Chiral Differentiation Quadrupolar Splitting 5 Chiral Chemical Shift Anisotropy 6 Chiral Dipolar Coupling 7 Visualizing Isotopic Chirality 8 Using Achiral Derivatizing Agents 9 Using Natural Abundance Deuterium 10 Summary 11 Biographical Sketches

参考文章(39)
Muriel Sarfati, Jacques Courtieu, Philippe Lesot, First successful enantiomeric discrimination of chiral alkanes using NMR spectroscopy Chemical Communications. pp. 1113- 1114 ,(2000) , 10.1039/B002806L
Denis Merlet, Bernard Ancian, Jacques Courtieu, Philippe Lesot, Two-Dimensional Deuterium NMR Spectroscopy of Chiral Molecules Oriented in a Polypeptide Liquid Crystal: Applications for the Enantiomeric Analysis through Natural Abundance Deuterium NMR Journal of the American Chemical Society. ,vol. 121, pp. 5249- 5258 ,(1999) , 10.1021/JA9837699
Denis Merlet, Muriel Sarfati, Bernard Ancian, Jacques Courtieu, Philippe Lesot, Description of natural abundance deuterium 2D-NMR experiments in weakly ordered liquid-crystalline solvents using a tailored cartesian spin-operator formalism Physical Chemistry Chemical Physics. ,vol. 2, pp. 2283- 2290 ,(2000) , 10.1039/B000834F
Alan S. Tracey, Keith Radley, Effects of composition on cholesteric behavior in the lyotropic mesophase system of potassium N-dodecanoyl-l-alaninate The Journal of Physical Chemistry. ,vol. 88, pp. 6044- 6048 ,(1984) , 10.1021/J150668A061
Shigenobu Sobajima, NMR Studies on Orientation of Liquid Crystals of Poly-γ-Benzyl-L-Glutamate in Magnetic Fields Journal of the Physical Society of Japan. ,vol. 23, pp. 1070- 1078 ,(1967) , 10.1143/JPSJ.23.1070
Jean-Louis Canet, Isabelle Canet, Jacques Courtieu, Sandrine Da Silva, Jacques Gelas, Yves Troin, Acetyl-d3 Chloride: A Convenient Nonchiral Derivatizing Agent (NCDA) for a Facile Enantiomeric Excess Determination of Amines through Deuterium NMR Journal of Organic Chemistry. ,vol. 61, pp. 9035- 9037 ,(1996) , 10.1021/JO961141F
I. Canet, A. Meddour, J. Courtieu, J. L. Canet, J. Salaun, New, and Accurate Method To Determine the Enantiomeric Purity of Amino Acids Based on Deuterium NMR in a Cholesteric Lyotropic Liquid Crystal Journal of the American Chemical Society. ,vol. 116, pp. 2155- 2156 ,(1994) , 10.1021/JA00084A070