Isothermal (vapour+liquid) equilibrium of (cyclic ethers+ chlorohexane) mixtures: Experimental results and SAFT modelling

作者: I. Bandrés , B. Giner , M.C. López , H. Artigas , C. Lafuente

DOI: 10.1016/J.JCT.2008.03.017

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摘要: Abstract Experimental data for the isothermal (vapour + liquid) equilibrium of mixtures formed by several cyclic ethers (tetrahydrofuran, tetrahydropyran, 1,3-dioxolane, and 1,4-dioxane) chlorohexane at temperatures (298.15 328.15) K are presented. results have been discussed in terms both, molecular characteristics pure compounds potential intermolecular interaction between them using thermodynamic information obtained earlier. Furthermore, influence temperature on these has explored discussed. Transferable parameters SAFT-VR approach together with standard combining rules used to model phase a description that is excellent agreement experimental provided.

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