Structural and Photophysical Properties of (2E)-3-[4-(Dimethylamino) Phenyl]-1-(Naphthalen-1-yl) Prop-2-en-1-One (DPNP) in Different Media
作者： Mehboobali Pannipara , Abdullah M Asiri , Khalid A Alamry , Ibrahim A Salem , Samy A El-Daly
DOI: 10.1007/S10895-014-1485-X
关键词:
摘要: The spectral and photophysical properties of a new chalcone derivative (2E)-3-[4-(dimethylamino) phenyl]-1-(naphthalen-1-yl) prop-2-en-1-one (DPNP) containing donor-acceptor group has been synthesized characterized on the basis (IR, 1HNMR & 13C NMR) X- ray crystallographic data. effect solvents parameters such as singlet absorption, molar absorptivity, oscillator strength, dipole moment, fluorescence spectra, quantum yield DPNP have investigated comprehensively. Significant red shift was observed in emission spectrum compared to absorption upon increasing solvent polarity, indicating higher moment excited state than ground state. difference between moments (Δμ) were obtained from Lippert-Mataga Reichardts correlations by means solvatochromic method. effects medium acidity electronic spectra studied. interaction with colloidal silver nanoparticles (AgNPs) also studied ethanol ethylene glycol using steady quenching measurements. data reveal that dynamic energy transfer play major role Ag NPs.
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sci-hub.se 参考文章(37)
Earl Wehry, Modern Fluorescence Spectroscopy ,(1976)
Paul Francis Gordon, Peter Gregory, Organic Chemistry in Colour ,(1983)
J. C. Scaiano, CRC handbook of organic photochemistry CRC Press. ,(1989)
S.R Inamdar, Y.F Nadaf, B.G Mulimani, Ground and excited state dipole moments of exalite 404 and exalite 417 UV laser dyes determined from solvatochromic shifts of absorption and fluorescence spectra Journal of Molecular Structure-theochem. ,vol. 624, pp. 47- 51 ,(2003) , 10.1016/S0166-1280(02)00734-0
Bilal Acemioğlu, Mustafa Arık, Hasan Efeoğlu, Yavuz Onganer, Solvent effect on the ground and excited state dipole moments of fluorescein Journal of Molecular Structure: THEOCHEM. ,vol. 548, pp. 165- 171 ,(2001) , 10.1016/S0166-1280(01)00513-9
Mehboobali Pannipara, Abdullah M Asiri, Khalid A Alamry, Ibrahim A Salem, Samy A El-Daly, None, Spectral behavior and photophysical parameters of (2Z)-3-[4-(dimethylamino) phenyl]-2-(4-fluorophenyl) prop-2-ene-nitrile (DPF) in different media Journal of Luminescence. ,vol. 157, pp. 163- 171 ,(2015) , 10.1016/J.JLUMIN.2014.08.053
Samy A El-Daly, Abdullah M Asiri, Khalid A Alamry, Abdullah Y Obaid, None, UV–visible absorption, fluorescence characteristics and laser activity of (E,E)-2,5-bis(4-methoxystyryl)pyrazine (BMSP) Journal of Luminescence. ,vol. 139, pp. 69- 78 ,(2013) , 10.1016/J.JLUMIN.2013.02.025
Alberto Credi, Luca Prodi, Inner filter effects and other traps in quantitative spectrofluorimetric measurements: Origins and methods of correction Journal of Molecular Structure. ,vol. 1077, pp. 30- 39 ,(2014) , 10.1016/J.MOLSTRUC.2014.03.028
Abdullah M Asiri, Salman A Khan, Muhammed S Al-Amoudi, Kalid A Alamry, None, Synthesis, Characterization, Absorbance, Fluorescence and Non Linear Optical Properties of Some Donor Acceptor Chromophores Bulletin of The Korean Chemical Society. ,vol. 33, pp. 1900- 1906 ,(2012) , 10.5012/BKCS.2012.33.6.1900
Shaomin Ji, Jun Yang, Qing Yang, Shasha Liu, Maodu Chen, Jianzhang Zhao, Tuning the intramolecular charge transfer of alkynylpyrenes: effect on photophysical properties and its application in design of OFF-ON fluorescent thiol probes. Journal of Organic Chemistry. ,vol. 74, pp. 4855- 4865 ,(2009) , 10.1021/JO900588E