Bimetallic Osmium−Tin Clusters: Addition of Triphenyltinhydride to Unsaturated [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] and Saturated [Os3(CO)10(μ-dppm)]

作者: Mohammad R Hassan , Graeme Hogarth , GM Golzar Hossain , Shariff E Kabir , Arun K Raha

DOI: 10.1021/OM7007716

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摘要: Reaction of electron-deficient [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] (2) with Ph3SnH at ambient temperature yields the bimetallic osmium−tin dihydride complexes [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(SnPh3)...

参考文章(47)
D. J. Cardin, S. A. Keppie, M. F. Lappert, Binuclear organometallic compounds. Part I. The amine elimination reaction for synthesis of compounds containing bonds between elements of group IV and transition metals Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 2594- 2598 ,(1970) , 10.1039/J19700002594
R. H. Blessing, Outlier Treatment in Data Merging Journal of Applied Crystallography. ,vol. 30, pp. 421- 426 ,(1997) , 10.1107/S0021889896014628
John M. Thomas, Brian F. G. Johnson, Gopinathan Sankar, David Gleeson, Sophie Hermans, Robert Raja, Solvent-Free, Low-Temperature, Selective Hydrogenation of Polyenes using a Bimetallic Nanoparticle Ru-Sn Catalyst Angewandte Chemie International Edition. ,vol. 40, pp. 1211- 1215 ,(2001) , 10.1002/1521-3773(20010401)40:7<1211::AID-ANIE1211>3.0.CO;2-P
D. Michael P. Mingos, Polyhedral skeletal electron pair approach Accounts of Chemical Research. ,vol. 17, pp. 311- 319 ,(1984) , 10.1021/AR00105A003
George W Huber, JW Shabaker, JA Dumesic, Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons Science. ,vol. 300, pp. 2075- 2077 ,(2003) , 10.1126/SCIENCE.1085597
Kazi A. Azam, Michael B. Hursthouse, Md. Rafiqul Islam, Shariff E. Kabir, K. M. Abdul Malik, Rashid Miah, Claas Sudbrake, Heinrich Vahrenkamp, Synthesis, structure and reactivity of triosmium clusters derived from the reactions of [Os3(CO)10(µ-dppm)] (dppm = Ph2PCH2PPh2) and [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] with PHPh2 Journal of The Chemical Society-dalton Transactions. pp. 1097- 1106 ,(1998) , 10.1039/A708733K
Shariff E Kabir, Md Arzu Miah, Nitai C Sarker, GM Golzar Hussain, Kenneth I Hardcastle, Ebbe Nordlander, Edward Rosenberg, None, Reactivity of the Unsaturated Triosmium Cluster Os3(CO)8(μ3-η2-Ph2PCH2P(Ph)C6H4)(μ-H) with Benzothiophene: Activation of a P−C Bond in Diphosphine and a C−H Bond in Benzothiophene Organometallics. ,vol. 24, pp. 3315- 3320 ,(2005) , 10.1021/OM050110K