Size effect on the magnetic property of CoAl2O4 nanopowders prepared by reverse micelle processing

作者: J. Chandradass , M. Balasubramanian , Ki Hyeon Kim

DOI: 10.1016/J.JALLCOM.2010.07.014

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摘要: Abstract Cobalt aluminate (CoAl2O4) nanopowders were synthesized by reverse microemulsion process using cyclohexane, a nonionic surfactant, and aqueous solutions of cobalt (II) nitrate hexahydrate aluminum nonahydrate. The influence water to surfactant molar ratio on the size powders has been studied. X-ray diffraction analysis shows that calcined at 1000 °C have single phase cubic spinel structure. average particles increases with increasing ratio. mean diameter varies between 42 57 nm. Fourier transform infrared spectra also confirm formation CoAl2O4. Magnetization study reveals CoAl2O4 sample exhibits superparamagnetic behavior.

参考文章(30)
Marcos Zayat, David Levy, Surface Area Study of High Area Cobalt Aluminate Particles Prepared by the Sol-Gel Method Journal of Sol-Gel Science and Technology. ,vol. 25, pp. 201- 206 ,(2002) , 10.1023/A:1020287307107
C. Jeffrey Brinker, George W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing ,(1990)
Richard A. Nyquist, Ronald O. Kagel, Infrared spectra of inorganic compounds (3800-45cm[-1]) Academic Press. ,(1971)
Jacques Livage, Marc Henry, Clément Sanchez, Sol-gel chemistry of transition metal oxides Progress in Solid State Chemistry. ,vol. 18, pp. 259- 341 ,(1988) , 10.1016/0079-6786(88)90005-2
Weidong Li, Jiazhi Li, Jingkun Guo, Synthesis and characterization of nanocrystalline CoAl2O4 spinel powder by low temperature combustion Journal of The European Ceramic Society. ,vol. 23, pp. 2289- 2295 ,(2003) , 10.1016/S0955-2219(03)00081-5
Trupti Upadhyay, R. V. Upadhyay, R. V. Mehta, V. K. Aswal, P. S. Goyal, CHARACTERIZATION OF A TEMPERATURE-SENSITIVE MAGNETIC FLUID Physical Review B. ,vol. 55, pp. 5585- 5588 ,(1997) , 10.1103/PHYSREVB.55.5585
Dabin Yu, Xiaoquan Sun, Jiwei Zou, Zirong Wang, Feng Wang, Kun Tang, Oriented assembly of Fe3O4 nanoparticles into monodisperse hollow single-crystal microspheres Journal of Physical Chemistry B. ,vol. 110, pp. 21667- 21671 ,(2006) , 10.1021/JP0646933