Ionic conductivity studies in PMMA/PVdF polymer blend electrolyte with lithium salts

作者: O. Mahendran , S. Rajendran

DOI: 10.1007/BF02375980

关键词:

摘要: Batteries using ionically conducting polymer membranes as electrolytes are very attractive, since the concept of power sources capable combining a high energy content with plasticity is appealing for consumer electronics market and in electric vehicle applications. Blend based composed poly (methylmethacrylate) (PMMA), Poly Vinylidene fluoride (PVdF), Lithium salt (LiX) (X=ClO4, BF4 CF3SO3) Dimethyl Phthalate (DMP) prepared solvent casting technique. The films have been characterized XRD, FTIR, Thermal SEM studies; effect complexing temperature on ionic conductivity also discussed. maximum value obtained solid electrolyte film at 303 K 4.2 × 10−3 S/cm.

参考文章(21)
V. D. Prisyazhnyi, V. I. Lisin, E. S. Lee, Low — Melting Salts and Glasses as Li- Battery Electrolytes Springer Netherlands. pp. 101- 110 ,(1996) , 10.1007/978-94-009-1643-2_7
Raymond Benedict Seymour, Raymond Seymour, Polymers for Engineering Applications ,(1987)
MME Jacob, SRS Prabaharan, S Radhakrishna, Effect of PEO addition on the electrolytic and thermal properties of PVDF-LiClO4 polymer electrolytes Solid State Ionics. ,vol. 104, pp. 267- 276 ,(1997) , 10.1016/S0167-2738(97)00422-0
O BOHNKE, G FRAND, M REZRAZI, C ROUSSELOT, C TRUCHE, Fast ion transport in new lithium electrolytes gelled with PMMA. 2. Influence of lithium salt concentration Solid State Ionics. ,vol. 66, pp. 105- 112 ,(1993) , 10.1016/0167-2738(93)90033-Y
M ARMAND, The history of polymer electrolytes Solid State Ionics. ,vol. 69, pp. 309- 319 ,(1994) , 10.1016/0167-2738(94)90419-7
Jan Przyłuski, Władysław Wieczorek, Increasing the conductivity of polymer solid electrolytes: A review Solid State Ionics. ,vol. 36, pp. 165- 169 ,(1989) , 10.1016/0167-2738(89)90163-X
WH Leong, DW James, Vibrational spectra of anhydrous lithium perchlorate in crystalline and molten states Australian Journal of Chemistry. ,vol. 22, pp. 499- 503 ,(1969) , 10.1071/CH9690499
Bruno Scrosati, Lithium Rocking Chair Batteries: An Old Concept? Journal of The Electrochemical Society. ,vol. 139, pp. 2776- 2781 ,(1992) , 10.1149/1.2068978