Synthesis, structure and properties of bis[N,N-bis(2-pyridylmethyl)amine-N-ethyl-2-pyridine-2-carboxamidecopper(II)] perchlorate
作者： John M Rowland , Marilyn M Olmstead , Pradip K Mascharak
DOI: 10.1016/S0020-1693(01)00798-8
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摘要: Abstract In this account we report the synthesis, structure and characterization of a dimeric Cu(II) complex, [Cu 2 (PaPy 3 H) ](ClO 4 ) (bis[ N,N -bis(2-pyridylmethyl)amine- N -ethyl-2-pyridine-2-carboxamidecopper(II)]). coordination designed ligand PaPy H to centers is completed by bis(picolyl)methyl amine portion one unit oxygen pyridine nitrogen atoms pyridine-2-carboxamide moiety second ligand. The resulting complex demonstrates new mode H.
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