Investigation on the chemiluminescence reaction of the phenylhydrazine‐luminol–peroxide system
作者： A. L. S. Chandel , S. A. Khan , R. S. Kher , Ashish Tiwari
DOI: 10.1002/BIO.1374
关键词:
摘要: We studied the chemiluminescence (CL) oxidation of phenyl hydrazine-luminol with various organic and inorganic peroxides. Maximum CL intensity for this system was obtained t-butylhydroperoxide. The enhancement in depended strongly on pH greatest at 12.5. solvent drastically enhanced intensity. DMSO found to increase many-fold as compared acetonitrile water. effect temperature has also been studied. spectra revealed a broad peak 425 nm, which suggests excited 3-aminophthalate ion luminophor. A mechanism explain reactions is suggested.
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