Functionalized long-chain olefin mixtures and uses therefor

作者: Brian W. Kolthammer , Thomas C. Eisenschmid , David A. Wilson , Kara S. Weber , Robert Kirk Thompson

DOI:

关键词:

摘要: Novel mixtures of long-chain (C10-C20) olefins are functionalized by conversion to aldehydes using an OXO process, or sulfates, sulfonates, sulfones, sulfides, sulfoxides direct sulfonation. The may then be hydrogenated form alcohols, aminated amines amides. starting mixture acquired as a byproduct the tetramerization ethylene in presence certain chromium-containing catalysts. mixtures, and derivatives prepared therefrom such alkoxylates from useful surfactants that offer improved performance many applications, while their preparation based on reduces cost also waste-handling issues for this non-targeted stream.

参考文章(23)
Rosa Laura Moese, Michael Stanford Showell, Jean-Luc Philippe Bettiol, Alfred Busch, Detergent compositions comprising a pectate lyase and a mid-branched anionic surfactant ,(1999)
Johan Paul Smit, Harry van der Heijden, Arie van Zon, Eric Johannes Maria De Boer, Quoc An On, Transition metal complexes ,(2005)
Edgar Zeller, Marc Walter, Klaus Diehl, Wolfgang Richter, Jürgen Tropsch, Michael Röper, C13 alcohol mixture and functionalised C13 alcohol mixture ,(2000)
George Francis Schaefer, George Edward Barker, Denis Forster, Detergent range aldehyde and alcohol mixtures and derivatives, and process therefor ,(1983)
Daniel Stedman Connor, Branched surfactant manufacture ,(1997)
David M. Singleton, Brendan Dermot Murray, Louis Kravetz, Highly branched primary alcohol compositions, and biodegradable detergents made therefrom ,(1997)
Kevin Blann, Annette Bollmann, John T. Dixon, Fiona M. Hess, Esna Killian, Hulisani Maumela, David H. Morgan, Arno Neveling, Stephanus Otto, Matthew J. Overett, Highly selective chromium-based ethylene trimerisation catalysts with bulky diphosphinoamine ligands Chemical Communications. pp. 620- 621 ,(2005) , 10.1039/B412431F
Annette Bollmann, John T. Dixon, Daleen Haasbroek, Esna Killian, Hulisani Maumela, David S. McGuinness, David H. Morgan, Matthew J. Overett, Kevin Blann, Mechanistic Investigations of the Ethylene Tetramerisation Reaction Journal of the American Chemical Society. ,vol. 127, pp. 10723- 10730 ,(2005) , 10.1021/JA052327B
Annette Bollmann, Kevin Blann, John T. Dixon, Fiona M. Hess, Esna Killian, Hulisani Maumela, David S. McGuinness, David H. Morgan, Arno Neveling, Stefanus Otto, Matthew Overett, Alexandra M. Z. Slawin, Peter Wasserscheid, Sven Kuhlmann, Ethylene Tetramerization: A New Route to Produce 1-Octene in Exceptionally High Selectivities Journal of the American Chemical Society. ,vol. 126, pp. 14712- 14713 ,(2004) , 10.1021/JA045602N
Kirk Herbert Raney, Charles Lee Edwards, Paul Gregory Shpakoff, Branched primary alcohol compositions and derivatives thereof ,(2001)