BODIPY decorated dendrimeric cyclotriphosphazene photosensitizers: synthesis and efficient singlet oxygen generators

作者: Esra Tanrıverdi Eçik , Elif Şenkuytu , Zeynep Cebesoy , Gönül Yenilmez Çiftçi

DOI: 10.1039/C6RA07171F

关键词:

摘要: In the present work, syntheses of BODIPY decorated dendrimeric cyclotriphosphazenes (8–10) are described. The newly synthesized have been characterized by 1H, 13C, 31P NMR spectroscopies, and UV-Vis electronic absorption spectra. These derivatives show in NIR region with good molar extinction coefficients. Singlet oxygen generation capacities novel compounds measured using trap molecule 1,3-diphenylisobenzofuran. demonstrate high singlet quantum yields. Also, each them shows chemical photostability under conditions measurement. proposed as potential photosensitizers that can be used efficient generators.

参考文章(36)
Anne-Marie Caminade, Aurélien Hameau, Jean-Pierre Majoral, The specific functionalization of cyclotriphosphazene for the synthesis of smart dendrimers Dalton Transactions. ,vol. 45, pp. 1810- 1822 ,(2016) , 10.1039/C5DT03047A
Samuel G. Awuah, Youngjae You, Boron dipyrromethene (BODIPY)-based photosensitizers for photodynamic therapy RSC Advances. ,vol. 2, pp. 11169- 11183 ,(2012) , 10.1039/C2RA21404K
Nagappanpillai Adarsh, Rekha R. Avirah, Danaboyina Ramaiah, Tuning Photosensitized Singlet Oxygen Generation Efficiency of Novel Aza-BODIPY Dyes Organic Letters. ,vol. 12, pp. 5720- 5723 ,(2010) , 10.1021/OL102562K
Jianzhang Zhao, Wanhua Wu, Jifu Sun, Song Guo, Triplet photosensitizers: from molecular design to applications Chemical Society Reviews. ,vol. 42, pp. 5323- 5351 ,(2013) , 10.1039/C3CS35531D
Nuran Asmafiliz, Zeynel Kılıç, Aslı Öztürk, Tuncer Hökelek, L Yasemin Koc, Leyla Açık, Özgül Kısa, Ali Albay, Zafer Üstündağ, Ali Osman Solak, None, Phosphorus-nitrogen compounds. 18. Syntheses, stereogenic properties, structural and electrochemical investigations, biological activities, and DNA interactions of new spirocyclic mono- and bisferrocenylphosphazene derivatives. Inorganic Chemistry. ,vol. 48, pp. 10102- 10116 ,(2009) , 10.1021/IC901039K
Aurore Loudet, Kevin Burgess, BODIPY dyes and their derivatives: syntheses and spectroscopic properties. Chemical Reviews. ,vol. 107, pp. 4891- 4932 ,(2007) , 10.1021/CR078381N
Gönül Yenilmez Çiftçi, Esra Tanrıverdi Eçik, Mustafa Bulut, Fatma Yuksel, Adem Kılıç, Mahmut Durmuş, Synthesis and characterization of dicoumarol substituted cyclotriphosphazenes Inorganica Chimica Acta. ,vol. 398, pp. 106- 112 ,(2013) , 10.1016/J.ICA.2012.12.019
Liang Yao, Shuzhang Xiao, Feijun Dan, Boron-Fluorine Photosensitizers for Photodynamic Therapy Journal of Chemistry. ,vol. 2013, pp. 1- 10 ,(2013) , 10.1155/2013/697850
Grégory Franc, Serge Mazères, Cédric-Olivier Turrin, Laure Vendier, Carine Duhayon, Anne-Marie Caminade, Jean-Pierre Majoral, Synthesis and properties of dendrimers possessing the same fluorophore(s) located either peripherally or off-center. Journal of Organic Chemistry. ,vol. 72, pp. 8707- 8715 ,(2007) , 10.1021/JO701462F