Methyl Oleate Production in a Supported Sol–Gel Immobilized Lipase Packed Bed Reactor
作者： Sarah M. Meunier , Amin R. Rajabzadeh , Trevor G. Williams , Raymond L. Legge
DOI: 10.1021/ACS.ENERGYFUELS.5B00176
关键词:
摘要: A supported immobilized lipase was investigated as a suitable biocatalyst for the transesterification of triolein to methyl oleate in packed bed reactor (PBR). The packing material bioreactor comprised sol–gel and on Celite (CSG). kinetic- mass transfer-based model developed, incorporating novel efficiency correlation account effect glycerol enzyme. Comparing CSG PBR performance that using commercial preparation (Novozym 435 (N435)), higher product conversion achievable over shorter time period, indicating superior enzymatic transesterification. rate equation accounting alcohol inhibition used compare kinetics N435 PBRs. It found exhibited maximum reaction less prone by methanol relative N435. resulting showed good agreement with experimental data, ex...
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