Substrate effects on formation and hydrogenation of Mg–Ni films

作者: Martynas Lelis , Darius Milcius , Dag Noréus

DOI: 10.1016/J.APSUSC.2012.09.028

关键词:

摘要: Abstract Usually metallic films for metal hydrides research applications are deposited on hard and flat substrates such as silicon, magnesium oxide, fused silica or quartz glass. With the film thickness increases all during hydrogenation deals with typical problems brittleness cracking. In this paper we demonstrate that Mg–Ni hydrogen storage can be successfully to flexible low surface energy expanded PTFE substrates. The received results soft (expanded PTFE) compared being crystalline silicon substrate without plasma pretreatment. It is observed different interface zone between has great affect both crystallinity its reaction hydrogen. also demonstrated modifying of might have microstructure before after hydrogenation.

参考文章(45)
P. Chen, Hydrogen Storage: Liquid and Chemical Reference Module in Earth Systems and Environmental Sciences#R##N#Comprehensive Renewable Energy. ,vol. 4, pp. 157- 177 ,(2012) , 10.1016/B978-0-08-087872-0.00414-5
Arthur A Tracton, None, Coatings Technology Handbook CRC Press. ,(2005) , 10.1201/9781420027327
Marcus Noble, Eric C. Apel, Edward K. C. Lee, The singlet π* ← n spectrum of jet‐cooled acetaldehyde Journal of Chemical Physics. ,vol. 78, pp. 2219- 2226 ,(1983) , 10.1063/1.445066
Helen Blomqvist, Dag Noréus, Mechanically reversible conductor–insulator transition in Mg2NiH4 Journal of Applied Physics. ,vol. 91, pp. 5141- 5148 ,(2002) , 10.1063/1.1461069
A. Borgschulte, J. H. Rector, H. Schreuders, B. Dam, R. Griessen, Electrohydrogenation of MgH2-thin films Applied Physics Letters. ,vol. 90, pp. 071912- ,(2007) , 10.1063/1.2695626
I.P. Jain, Pragya Jain, Ankur Jain, Novel hydrogen storage materials: A review of lightweight complex hydrides Journal of Alloys and Compounds. ,vol. 503, pp. 303- 339 ,(2010) , 10.1016/J.JALLCOM.2010.04.250
Anna-Maria Janner, Paul van der Sluis, Virginie Mercier, Cycling durability of switchable mirrors Electrochimica Acta. ,vol. 46, pp. 2173- 2178 ,(2001) , 10.1016/S0013-4686(01)00371-1
U Laudahn, A Pundt, M Bicker, U v. Hülsen, U Geyer, T Wagner, R Kirchheim, Hydrogen-induced stress in Nb single layers Journal of Alloys and Compounds. ,vol. 293, pp. 490- 494 ,(1999) , 10.1016/S0925-8388(99)00471-5
T. Mitsuda, H. Taguchi, Formation of magnesium silicate hydrate and its crystallization to talc Cement and Concrete Research. ,vol. 7, pp. 223- 230 ,(1977) , 10.1016/0008-8846(77)90083-7