Resorcinol-Formaldehyde (RF) as a Novel Plasticizer for Starch-Based Solid Biopolymer Electrolyte.
作者： Vidhya Selvanathan , Mohd Hafidz Ruslan , Mohammod Aminuzzaman , Ghulam Muhammad , N. Amin
关键词:
摘要: A starch-resorcinol-formaldehyde (RF)-lithium triflate (LiTf) based biodegradable polymer electrolyte membrane was synthesized via the solution casting technique. The formation of RF crosslinks in starch matrix found to repress starch’s crystallinity as indicated by XRD data. Incorporation plasticizer improved conductivity greatly, with highest room-temperature recorded being 4.29 × 10−4 S cm−1 achieved starch:LiTf:RF (20 wt.%:20 wt.%:60 wt.%) composition. enhancement ionic an implication increase polymeric amorphous region concurrent suppression crystallinity. Chemical complexation between plasticizer, starch, and lithium salt components confirmed FTIR spectra.
mdpi.com
sci-hub.st 参考文章(35)
TETSUO KONDO, The assignment of IR absorption bands due to free hydroxyl groups in cellulose Cellulose. ,vol. 4, pp. 281- 292 ,(1997) , 10.1023/A:1018448109214
K. H. Teoh, Chin-Shen Lim, Chiam-Wen Liew, S. Ramesh, S. Ramesh, Electric double-layer capacitors with corn starch-based biopolymer electrolytes incorporating silica as filler Ionics. ,vol. 21, pp. 2061- 2068 ,(2015) , 10.1007/S11581-014-1359-X
S. Wang, Jinglin Yu, W. Gao, J. Pang, Jiugao Yu, Using X-ray diffractometry for identification of Fritillaria preparations according to geographical origin Pharmaceutical Chemistry Journal. ,vol. 40, pp. 572- 575 ,(2006) , 10.1007/S11094-006-0196-2
Olivia V López, María A García, Noemí E Zaritzky, None, Film forming capacity of chemically modified corn starches. Carbohydrate Polymers. ,vol. 73, pp. 573- 581 ,(2008) , 10.1016/J.CARBPOL.2007.12.023
Kris Frost, Daniel Kaminski, Gemma Kirwan, Edmond Lascaris, Robert Shanks, Crystallinity and structure of starch using wide angle X-ray scattering Carbohydrate Polymers. ,vol. 78, pp. 543- 548 ,(2009) , 10.1016/J.CARBPOL.2009.05.018
K.H. Teoh, Chin-Shen Lim, S. Ramesh, Lithium ion conduction in corn starch based solid polymer electrolytes Measurement. ,vol. 48, pp. 87- 95 ,(2014) , 10.1016/J.MEASUREMENT.2013.10.040
M.S. Su’ait, M.Y.A. Rahman, A. Ahmad, Review on polymer electrolyte in dye-sensitized solar cells (DSSCs) Solar Energy. ,vol. 115, pp. 452- 470 ,(2015) , 10.1016/J.SOLENER.2015.02.043
Canhui Cai, Cunxu Wei, In situ observation of crystallinity disruption patterns during starch gelatinization Carbohydrate Polymers. ,vol. 92, pp. 469- 478 ,(2013) , 10.1016/J.CARBPOL.2012.09.073
N SCHWANDT, T GOUND, Resorcinol-formaldehyde resin "Russian Red" endodontic therapy Journal of Endodontics. ,vol. 29, pp. 435- 437 ,(2003) , 10.1097/00004770-200307000-00002
S. Ramesh, R. Shanti, Ezra Morris, Studies on the plasticization efficiency of deep eutectic solvent in suppressing the crystallinity of corn starch based polymer electrolytes Carbohydrate Polymers. ,vol. 87, pp. 701- 706 ,(2012) , 10.1016/J.CARBPOL.2011.08.047