Solvent Effects on the Rate of Radiation-Induced Grafting of Vinyl Monomers on Polymeric Films

摘要: Abstract Earlier work indicated that in the radiation-induced grafting of vinyl monomers on polymeric films, plasticity film being grafted is determined by Hildebrand solubility parameter solution. Film affects termination step reaction, and thus strongly influences overall rate monomer film. In styrene nylon film, a sequence irradiation runs was made at selected volume ratios styrene/benzene/methanol, all solutions having constant value 9.5 Under these conditions, linear plot vs percent solution obtained. A similar pentafluorostyrene also produced PFS. Styrene polyethylene four using dissolved methanol, ethanol, 1-propanol, and...