Toward the Synthesis of Muironolide A: Synthesis and Structure of Heteroleptic Lanthanide–Terpyridine Complexes with 2-Oxo Amides
作者： Kyle Young , Qing Xiao , Armen Zakarian
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摘要: A lanthanide-catalyzed intramolecular Diels–Alder (IMDA) reaction en route to the synthesis of muironolide is described, along with detailed crystallographic structural studies lanthanide complexes between β-oxo amides and terpyridine. The X-ray are first examples nonsymmetric heteroleptic lanthanides carbonyl compounds, which reveal several properties that could be exploited in development catalytic reactions lanthanides.
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