LIF MEASUREMENTS AND CHEMICAL KINETIC ANALYSIS OF NITRIC OXIDE FORMATION IN HIGH-PRESSURE COUNTERFLOW PARTIALLY PREMIXED AND NONPREMIXED FLAMES

作者: SAMEER V. NAIK , NORMAND M. LAURENDEAU

DOI: 10.1080/00102200490504472

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摘要: We report quantitative, spatially resolved, linear laser-induced fluorescence (LIF) measurements of nitric oxide concentration ([NO]) in laminar, methane/air counterflow partially premixed and nonpremixed flames at six pressures up to 15 atm using excitation near 226.03 nm the γ(0,0) band NO. For flames, fuel-side equivalence ratios (φB) 1.45, 1.6, 2.0 are studied a global strain rate 20 s−1. complete set NO rates 20 s−1, 30 s−1, 40 s−1 is presented supplement previously reported data such flames. The quantitative compared with predictions from an opposed-flow flame code utilizing two GRI chemical kinetic mechanisms (versions 2.11 3.0). effect radiative heat loss on assessed by modified version that considers radiation optically thin limit. LIF [NO] corrected for variations electronic ...

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