Vitrification and Glass Transition of Water: Insights from Spin Probe ESR
作者： Shrivalli N. Bhat , Ajay Sharma , S. V. Bhat
DOI: 10.1103/PHYSREVLETT.95.235702
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摘要: Three long-standing problems related to the physics of water, viz., possibility vitrifying bulk water by rapid quenching, its glass transition, and supposed impossibility obtaining supercooled between 150 233 K, so-called "no man's land" phase diagram, are studied using highly sensitive technique spin probe ESR. Our results suggest that can indeed be vitrified quenching; it undergoes a transition at approximately 135 relaxation behavior this method 165 K closely follows predictions Adam-Gibbs model.
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