作者: Olfa Glaied , Christelle Delaite , Guy Hurtrez , Mathieu Joubert , Philippe Dumas
DOI: 10.1002/POLA.20704
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摘要: Well-defined macromonomers of poly(ethylene oxide) and poly(tert-butyl methacrylate) were obtained by anionic polymerization induced directly the carbanion issued from 2-methyl-2-oxazoline. When ethylene oxide was added to this with lithium as counterion, a new compound able initiate e-caprolactone in an anionically coordinated way synthesized, led well-defined poly(e-caprolactone) macromonomers. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Chem 43: 2440–2447,