Well defined difluorogold(iii) complexes supported by N-ligands.

作者: Mohammad Albayer , Robert Corbo , Jason L. Dutton

DOI: 10.1039/C8CC02535E

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摘要: Stable difluorogold(III) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(I) precursors using XeF2 or from tricationic Au(III) by displacement the N-ligands fluoride economical KF. X-ray crystallographic studies bisimidazole ligated derivative shows shortest Au–F bond known in a gold complex.

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