Liquid Crystalline π-Conjugated Copolymers Bearing a Pyrimidine Type Mesogenic Group
作者： Kohsuke Kawabata , Hiromasa Goto
DOI: 10.3390/MA2010022
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摘要: Phenylene-thiophene-based liquid crystalline π-conjugated copolymers bearing mesogenic groups as side chains were synthesized via a Stille polycondensation reaction and confirmed to exhibit nematic crystal phase at appropriate temperatures. The formation of phase, but not smectic indicates cooperation the main chain in main-chain/side-chain phase. generation polarons charge carriers during in-situ vapor doping iodine is increase with progresses, exhibiting Dysonian paramagnetic behavior typical conductive polymers.
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