Synthesis, structure and catalytic properties of Re(I)–NOBIN Schiff base complex
作者： Zheng-Kai Li , Yang Li , Liang Lei , Chi-Ming Che , Xiang-Ge Zhou
DOI: 10.1016/J.INOCHE.2004.12.020
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摘要: Abstract The chiral mononuclear complex of Re(I)–NOBIN Schiff base (NOBIN = 1-amino-1′-hydroxylbinaphthyl) was synthesized via the reaction Re(CO)5Cl and corresponding tridentate ligand in methanol. structure analysis reveals that central metal coordinates with nitrogen atom imine oxygen salicylaldehyde form a six-membered ring, while left uncoordinated phenol group adjacent to binaphthyl backbone forms hydrogen bonding water molecule coordinated Re(I) ion. This shows some catalytic ability asymmetric epoxidation aziridination moderate results.
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