Morphology-controlled synthesis of α-alumina microplatelets through an additive-assisted molten salt reaction

作者: Minmin Zhang , Yunfei Chang , Nuerxida Pulati , Shantao Zhang , Yuan Sun

DOI: 10.1016/J.MATLET.2017.09.025

关键词:

摘要: Abstract Highly dispersed α-Al2O3 microplatelets of various sizes and aspect ratios were prepared by additive-assisted molten salt synthesis. The effects SiO2 SiO2 + CaO additions on phase formation morphology development particles investigated. Introducing additives are very effective in controlling morphology. additive significantly enhances shape anisotropy platelets, where a particle ratio ∼23.8 was achieved, about 2.7–6.0 times higher than those the platelets without additives. When using mixture, low concentration facilitates growth large (∼9.8 µm), while increasing its content dramatically reduces platelet size to ∼3.7 µm. These findings provide new insight for design synthesis novel advanced anisotropic microcrystals with improved quality.

参考文章(14)
Hong Chen, Qidan Wu, Tianxi Yang, Mengqi Li, Hucheng Xie, Cong Lin, The influence of different titanium sources on flaky α-Al2O3 prepared by molten salt synthesis Ceramics International. ,vol. 41, pp. 12288- 12294 ,(2015) , 10.1016/J.CERAMINT.2015.06.054
Li-Qian Cheng, Ke Wang, Jing-Feng Li, Synthesis of complex niobate nanostructures via molten-salt reaction: Effect of ZrO2 on product morphology Materials Letters. ,vol. 138, pp. 128- 131 ,(2015) , 10.1016/J.MATLET.2014.09.096
Yunfei Chang, Raul Bermejo, Gary L. Messing, Improved Fracture Behavior of Alumina Microstructural Composites with Highly Textured Compressive Layers Journal of the American Ceramic Society. ,vol. 97, pp. 3643- 3651 ,(2014) , 10.1111/JACE.13168
Zhu Li-hui, Huang Qing-wei, Morphology control of α-Al2O3 platelets by molten salt synthesis Ceramics International. ,vol. 37, pp. 249- 255 ,(2011) , 10.1016/J.CERAMINT.2010.09.021
Hae Jeong Kim, Tae Gun Kim, Jeong Ja Kim, Seong Soo Park, Seong Soo Hong, Gun Dae Lee, Influences of precursor and additive on the morphology of nanocrystalline α-alumina Journal of Physics and Chemistry of Solids. ,vol. 69, pp. 1521- 1524 ,(2008) , 10.1016/J.JPCS.2007.10.024
P. Billik, M. Čaplovičová, L. Čaplovič, B. Horváth, Mechanochemical-molten salt synthesis of α-Al2O3 platelets Ceramics International. ,vol. 41, pp. 8742- 8747 ,(2015) , 10.1016/J.CERAMINT.2015.03.095
Nelson S. Bell, Seung-Beom Cho, James H. Adair, Size Control of α‐Alumina Particles Synthesized in 1,4‐Butanediol Solution by α‐Alumina and α‐Hematite Seeding Journal of the American Ceramic Society. ,vol. 81, pp. 1411- 1420 ,(2005) , 10.1111/J.1151-2916.1998.TB02498.X
L. J. Bonderer, A. R. Studart, L. J. Gauckler, Bioinspired design and assembly of platelet reinforced polymer films. Science. ,vol. 319, pp. 1069- 1073 ,(2008) , 10.1126/SCIENCE.1148726
Yunfei Chang, Stephen Poterala, Doruk Yener, Gary L Messing, Fabrication of Highly Textured Fine‐Grained α‐Alumina by Templated Grain Growth of Nanoscale Precursors Journal of the American Ceramic Society. ,vol. 96, pp. 1390- 1397 ,(2013) , 10.1111/JACE.12286