Novel water-soluble metallophthalocyanines supported on cotton fabric
作者： Özgür Yıldırım , Altuğ M Sevim , Ahmet Gül
DOI: 10.1111/J.1478-4408.2012.00368.X
关键词:
摘要: In this study, two novel phthalonitrile derivatives were firstly prepared starting from 4-nitrophthalonitrile: substitution of the nitro group with 3-mercaptopropionic acid and 4-mercaptobenzoic gave precursors, namely, 4-(carboxyethylsulphanyl) 4-(carboxyphenylsulphanyl)phthalonitrile. Zinc(ii), copper(ii) cobalt(ii) metallophthalocyanines bearing four carboxylic groups on periphery by cyclotetramerisation new precursors in presence corresponding divalent metal salts. The compounds characterised elemental analyses, infrared, ultraviolet–visible, mass proton nuclear magnetic resonance techniques. All these newly synthesised water-soluble metallophthalocyanine supported cationic cotton fabrics ammonia solution sodium hydroxide dyeing effectiveness, levelness fastness dyed investigated. These are considered to be useful textile industry also optical catalytic applications, especially for air-purifying materials air conditioners.
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