Mechanism of hexavalent chromium removal by dead fungal biomass of Aspergillus niger.

作者: Donghee Park , Yeoung-Sang Yun , Ji Hye Jo , Jong Moon Park

DOI: 10.1016/J.WATRES.2004.11.002

关键词:

摘要: When synthetic wastewater containing Cr(VI) was placed in contact with the dead fungal biomass of Aspergillus niger, completely removed from aqueous solution, whereas Cr(III), which not initially present, appeared solution. Desorption and X-ray photoelectron spectroscopy (XPS) studies showed that most Cr bound on trivalent form. These results indicated main mechanism removal a redox reaction between biomass, is quite different previously reported mechanisms. The influences time, pH, concentration, concentration temperature were also evaluated. rate increased decrease pH increases temperature. Although kinetics dependent experimental conditions, In conclusion, new by has been proposed. From practical viewpoint, this abundant inexpensive potential application conversion toxic into less or nontoxic Cr(III).

参考文章(26)
R Sudha Bai, T.Emilia Abraham, Studies on chromium(VI) adsorption-desorption using immobilized fungal biomass. Bioresource Technology. ,vol. 87, pp. 17- 26 ,(2003) , 10.1016/S0960-8524(02)00222-5
Andrew Eaton, A.E. Greenberg, Lenore S. Clesceri, Standard methods for the examination of water and wastewater Published in <b>1998</b> in Washington DC) by American public health association. ,(1992)
J. Rios, J.G. Parsons, G. Gamez, J.L. Gardea-Torresdey, K.J. Tiemann, V. Armendariz, L. Bess-Oberto, R.R. Chianelli, Characterization of Cr(VI) binding and reduction to Cr(III) by the agricultural byproducts of Avena monida (Oat) biomass Journal of Hazardous Materials. ,vol. 80, pp. 175- 188 ,(2000) , 10.1016/S0304-3894(00)00301-0
David Kratochvil, Patricia Pimentel, Bohumil Volesky, Removal of trivalent and hexavalent chromium by seaweed biosorbent Environmental Science & Technology. ,vol. 32, pp. 2693- 2698 ,(1998) , 10.1021/ES971073U
Donghee Park, Yeoung-Sang Yun, Jong Moon Park, Reduction of hexavalent chromium with the brown seaweed Ecklonia biomass. Environmental Science & Technology. ,vol. 38, pp. 4860- 4864 ,(2004) , 10.1021/ES035329+
Arup K. Sengupta, Dennis Clifford, Chromate ion exchange mechanism for cooling water Industrial & Engineering Chemistry Fundamentals. ,vol. 25, pp. 249- 258 ,(1986) , 10.1021/I100022A012
Laurent Dambies, Claude Guimon, Sotira Yiacoumi, Eric Guibal, Characterization of metal ion interactions with chitosan by X-ray photoelectron spectroscopy Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 177, pp. 203- 214 ,(2001) , 10.1016/S0927-7757(00)00678-6
Vinay K. Singh, Prem N. Tiwari, Removal and Recovery of Chromium(VI) from Industrial Waste Water Journal of Chemical Technology & Biotechnology. ,vol. 69, pp. 376- 382 ,(1997) , 10.1002/(SICI)1097-4660(199707)69:3<376::AID-JCTB714>3.0.CO;2-F
Anil Baral, Robert D. Engelken, Chromium-based regulations and greening in metal finishing industries in the USA Environmental Science & Policy. ,vol. 5, pp. 121- 133 ,(2002) , 10.1016/S1462-9011(02)00028-X