Synthesis, photophysics and photochemistry studies on non-peripherally tetra-substituted Zn(II) and In(III) phthalocyanines bearing ferulic acid units
作者： Semih Gorduk
DOI: 10.1016/J.MOLSTRUC.2019.126921
关键词:
摘要: Abstract In this study, we reported synthesis, characterization, photophysical, photochemical and aggregation properties of new non-peripherally tetra-substituted Zn(II) (FA-ZnPc) In(III) (FA-InPc) phthalocyanine photosensitizers bearing ferulic acid units. The synthesized compounds were characterized by Elemental analysis, FT-IR, UV–vis, NMR MS techniques. Aggregation behaviors these phthalocyanines studied in various solvents such as DMSO, DMF, THF no was detected the mentioned for both phthalocyanines. addition, photophysical (Fluorescence quantum yield) (Singlet oxygen yield photodegradation examined solvents. results showed that FA-ZnPc has highest singlet DMSO. Further, studies FA-InPc owing to their high yields different (range from 0.65 0.96) can be used photodynamic therapy (PDT).
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