IMMOBILIZATION AND STABILIZATION OF TiO 2 NANOPARTICLES IN ALKALINE- SOLIDIFICATED CHITOSAN SPHERES WITHOUT CROSS-LINKING AGENT

作者: Alexandru Mihai Grumezescu , Keng-Shiang Huang , Chih-Hui Yang , Chih-Yu Wang , Ching-Yun Chang

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摘要: TiO2 nanoparticles have been shown to wide applications in multiple fields. The combining of polymer and form films or hydrogel materials has further advantages such as reusable, non-aggregated, recyclable good dispersible. Although the chitosan particles can be easily obtained by crosslinking method, cytotoxicity some commonly used agents made it limited biological applications. In this article, a facile approach synthesis nanoparticles- composite spheres without was presented. proposed stabilize disperse matrix, an alkaline solidification process. diameter synthesized is ranging from 1.5 mm 2.5 mm. With UV-Visible spectroscopy, EDS, XRD FTIR, were embedded spheres. fabricated are potential for multi-filed applications, bactericide, wastewater pollutant treatment, others.

参考文章(39)
Ming Shien Yen, Yun Hwei Shen, Sheau Ming Chen, Effect of chitosan biopolymer and UV/TiO 2 method for the de-coloration of acid blue 40 simulated textile wastewater African Journal of Biotechnology. ,vol. 9, pp. 5575- 5580 ,(2010) , 10.5897/AJB10.005
R. Jayakumar, Roshni Ramachandran, P.T. Sudheesh Kumar, V.V. Divyarani, Sowmya Srinivasan, K.P. Chennazhi, H. Tamura, S.V. Nair, Fabrication of Chitin-chitosan/nano TiO2-Composite Scaffolds for Tissue Engineering Applications International Journal of Biological Macromolecules. ,vol. 49, pp. 274- 280 ,(2011) , 10.1016/J.IJBIOMAC.2011.04.020
Wilson A. Lee, Nadine Pernodet, Bingquan Li, Chien H. Lin, Eli Hatchwell, Miriam H. Rafailovich, Multicomponent polymer coating to block photocatalytic activity of TiO2 nanoparticles. Chemical Communications. pp. 4815- 4817 ,(2007) , 10.1039/B709449C
Zulkarnain Zainal, Lee Kong Hui, Mohd Zobir Hussein, Abdul Halim Abdullah, Imad (Moh’d Khair) Rashid Hamadneh, Characterization of TiO2–Chitosan/Glass photocatalyst for the removal of a monoazo dye via photodegradation–adsorption process Journal of Hazardous Materials. ,vol. 164, pp. 138- 145 ,(2009) , 10.1016/J.JHAZMAT.2008.07.154
L. Cordero-Arias, S. Cabanas-Polo, Haoxiang Gao, J. Gilabert, E. Sanchez, J. A. Roether, D. W. Schubert, S. Virtanen, A. R. Boccaccini, Electrophoretic deposition of nanostructured-TiO2/chitosan composite coatings on stainless steel RSC Advances. ,vol. 3, pp. 11247- 11254 ,(2013) , 10.1039/C3RA40535D
Chih-Hui Yang, Chih-Yu Wang, Keng-Shiang Huang, Chen-Sheng Yeh, Andrew H. -J. Wang, Wei-Ting Wang, Ming-Yu Lin, Facile Synthesis of Radial-Like Macroporous Superparamagnetic Chitosan Spheres with In-Situ Co-Precipitation and Gelation of Ferro-Gels PLoS ONE. ,vol. 7, pp. e49329- ,(2012) , 10.1371/JOURNAL.PONE.0049329
Amit Jaiswal, Siddhartha Sankar Ghsoh, Arun Chattopadhyay, Quantum Dot Impregnated-Chitosan Film for Heavy Metal Ion Sensing and Removal Langmuir. ,vol. 28, pp. 15687- 15696 ,(2012) , 10.1021/LA3027573
E. Mirzaei B., A. Ramazani S. A., M. Shafiee, M. Danaei, Studies on Glutaraldehyde Crosslinked Chitosan Hydrogel Properties for Drug Delivery Systems International Journal of Polymeric Materials. ,vol. 62, pp. 605- 611 ,(2013) , 10.1080/00914037.2013.769165
P SANPUI, A MURUGADOSS, P PRASAD, S GHOSH, A CHATTOPADHYAY, The antibacterial properties of a novel chitosan-Ag-nanoparticle composite. International Journal of Food Microbiology. ,vol. 124, pp. 142- 146 ,(2008) , 10.1016/J.IJFOODMICRO.2008.03.004