Magnetic properties and magnetocaloric effect in the rare earth-rich phases RE4PtMg (RE = Ho and Er)

作者: Lingwei Li , Oliver Niehaus , Marcel Kersting , Rainer Pöttgen

DOI: 10.1016/J.INTERMET.2015.03.004

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摘要: Abstract The magnetic and magnetocaloric properties of Ho4PtMg Er4PtMg with cubic Gd4RhIn-type structure have been investigated by magnetization heat capacity measurements. compounds undergo a second order phase transition from paramagnetic to ferromagnetic state at Curie temperatures TC ∼ 28 16 K for Er4PdMg, respectively. A large reversible MCE was observed around TC both compounds. For field change 0–7 T, the maximum values entropy (−ΔSMmax) are 16.9 22.5 J/kg K Er4PtMg, corresponding adiabatic temperature (ΔTadmax) 5.3 6.5 K.

参考文章(28)
Ahmet Doğan, Sudhindra Rayaprol, Rainer Pöttgen, Structure and magnetic properties of RE4CoCd and RE4RhCd (RE = Tb, Dy, Ho) Journal of Physics: Condensed Matter. ,vol. 19, pp. 076213- ,(2007) , 10.1088/0953-8984/19/7/076213
Selcan Tuncel, Wilfried Hermes, Bernard Chevalier, Ute Ch. Rodewald, Rainer Pöttgen, Ternary Magnesium Compounds RE23Ni7Mg4 (RE = La, Ce, Pr, Nd, Sm) with Pr23Ir7Mg4 Type Structure† Zeitschrift für anorganische und allgemeine Chemie. ,vol. 634, pp. 2140- 2144 ,(2008) , 10.1002/ZAAC.200800071
M. H. Phan, G. T. Woods, A. Chaturvedi, S. Stefanoski, G. S. Nolas, H. Srikanth, Long-range ferromagnetism and giant magnetocaloric effect in type VIII Eu8Ga16Ge30 clathrates Applied Physics Letters. ,vol. 93, pp. 252505- ,(2008) , 10.1063/1.3055833
Shi X Dou, Jianli Wang, AJ Studer, Rong Zeng, Stewart J Campbell, John M Cadogan, None, Magnetocaloric effect in layered NdMn2Ge0.4Si1.6 Applied Physics Letters. ,vol. 98, pp. 232509- ,(2011) , 10.1063/1.3599456
B Li, WJ Hu, XG Liu, F Yang, WJ Ren, XG Zhao, ZD Zhang, None, Large reversible magnetocaloric effect in TbCoC(2) in low magnetic field Applied Physics Letters. ,vol. 92, pp. 242508- ,(2008) , 10.1063/1.2948900
Ute Ch. Rodewald, Selcan Tuncel, Bernard Chevalier, Rainer Pöttgen, Rare Earth Metal‐Rich Magnesium Compounds RE4IrMg (RE = Y, La, Pr, Nd, Sm, Gd, Tb, Dy) and RE23Ir7Mg4 (RE = La, Ce, Pr, Nd) Zeitschrift für anorganische und allgemeine Chemie. ,vol. 634, pp. 1011- 1016 ,(2008) , 10.1002/ZAAC.200700552
Yikun Zhang, Baijun Yang, Effect of Fe substitution on magnetocaloric effect in metamagnetic boron-carbide ErNi2−xFexB2C compounds Journal of Alloys and Compounds. ,vol. 610, pp. 540- 543 ,(2014) , 10.1016/J.JALLCOM.2014.05.008
Roman Zaremba, Ute Ch. Rodewald, Rolf-Dieter Hoffmann, Rainer Pöttgen, The Rare Earth Metal-Rich Indides RE 4RhIn (RE = Gd–Tm, Lu) Monatshefte für Chemie - Chemical Monthly. ,vol. 138, pp. 523- 528 ,(2007) , 10.1007/S00706-007-0663-9
Samuel Couillaud, Stefan Linsinger, Cédric Duée, Aline Rougier, Bernard Chevalier, Rainer Pöttgen, Jean-Louis Bobet, Hydrogenation behavior of the solid solutions RE4NiMg1−xAlx and RE4−yNiMg1+y with RE = Gd and Y Intermetallics. ,vol. 18, pp. 1115- 1121 ,(2010) , 10.1016/J.INTERMET.2010.02.007