Reshaping Rubrene by Controlled Reduction with Alkali Metals
作者： Alexander V. Zabula , Natalie J. Sumner , Alexander S. Filatov , Sarah N. Spisak , Vladimir M. Grigoryants
关键词:
摘要: Mono-, di- and tetraanions of rubrene, (C42H28, Rub0), were generated by the controlled reduction neutral polyarene with various alkali metals in appropriate solvent. The X-ray diffraction studies resulting adducts Rub1–, Rub2– Rub4– alkali-metal ions revealed distortion rubrene core upon stepwise acquisition electrons. Coordination Cs+ ion a noticeable deformation Rub1– are observed at first step. Two types dianions showing an essentially different conformation coordination environment for central tetracene have been seen cesium adduct Rub2–. Various supramolecular assembly between tetrareduced anion, Rub4–, lithium or rubidium cations found corresponding products solid state. structures anions their aggregation solution studied ESR multinuclear NMR (1H, 13C, 7Li 133Cs) spectroscopy.
sci-hub.se 参考文章(71)
Mordecai Rabinovitz, Polycyclic anions: From doubly to highly charged π-conjugated systems Topics in Current Chemistry. ,vol. 146, pp. 99- 169 ,(1988) , 10.1007/BFB0111256
Nina V. Kozhemyakina, Jürgen Nuss, Martin Jansen, Synthesis and Crystal Structure of a New C602-Fulleride: [K(DB24C8)(DME)]2C60·DME European Journal of Inorganic Chemistry. ,vol. 2009, pp. 3900- 3903 ,(2009) , 10.1002/EJIC.200900542
H. Bock, K. Gharagozloo-Hubmann, M. Sievert, T. Prisner, Z. Havlas, Single crystals of an ionic anthracene aggregate with a triplet ground state Nature. ,vol. 404, pp. 267- 269 ,(2000) , 10.1038/35005048
Alexander S. Filatov, Marina A. Petrukhina, Probing the binding sites and coordination limits of buckybowls in a solvent-free environment: Experimental and theoretical assessment Coordination Chemistry Reviews. ,vol. 254, pp. 2234- 2246 ,(2010) , 10.1016/J.CCR.2010.05.004
Martin Baumgarten, Lileta Gherghel, Manfred Wagner, Amir Weitz, Mordecai Rabinovitz, Pei-Chao Cheng, Lawrence T. Scott, Corannulene Reduction: Spectroscopic Detection of All Anionic Oxidation States Journal of the American Chemical Society. ,vol. 117, pp. 6254- 6257 ,(1995) , 10.1021/JA00128A012
A. F. Morpurgo, Vitaly Podzorov, Michael Gershenson, R. W.I. De Boer, Organic single-crystal field-effect transistors Physica Status Solidi (a). ,vol. 201, pp. 1302- 1331 ,(2004) , 10.1002/PSSA.200404336
Christoph Janiak, Stefan Mühle, Holger Hemling, Klaus Köhler, The solid-state structure of K3C60(THF)14 Polyhedron. ,vol. 15, pp. 1559- 1563 ,(1996) , 10.1016/0277-5387(95)00482-3
Sven Krieck, Helmar Görls, Matthias Westerhausen, Alkali Metal-Stabilized 1,3,5-Triphenylbenzene Monoanions: Synthesis and Characterization of the Lithium, Sodium, and Potassium Complexes† Organometallics. ,vol. 29, pp. 6790- 6800 ,(2010) , 10.1021/OM1009632
Marina A. Petrukhina, Alexander S. Filatov, Yulia Sevryugina, Kristian W. Andreini, Satoshi Takamizawa, Paracyclophanes as Versatile π-Donor Ligands Directing Formation of Extended Organometallic Networks Organometallics. ,vol. 25, pp. 2135- 2142 ,(2006) , 10.1021/OM051100M