Structural and surface patterning studies of N3-metalated adenine-copper complexes involving metal-olefin interaction
作者： Ashutosh Kumar Mishra , Chandra Shekhar Purohit , Jitendra Kumar , Sandeep Verma , None
DOI: 10.1016/J.ICA.2008.02.028
关键词:
摘要: We report the synthesis, solid state structural characterization and direct surface patterning of two adenine-copper(I) complexes. The ligand, 9-allyladenine, exhibits Cu(I) coordination via an N3-M-N7 mode by invoking participation from allylic double bond acetonitrile solvent molecule to result in EPR silent complex. Detailed crystal structure studies polymer thus formed were followed NMR ascertain Cu(I)-olefin interaction occurring substituent at N9 position. On air exposure, was substituted a water affording unique example water-bound Direct deposition these complexes on graphite resulted pattern which could be readily correlated structure.
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