Highly versatile Pd-thioether-phosphite catalytic systems for asymmetric allylic alkylation, amination, and etherification reactions.
作者： Mercè Coll , Oscar Pàmies , Montserrat Diéguez
DOI: 10.1021/OL500758Y
关键词:
摘要: A Pd-furanoside thioether-phosphite catalytic system that can create new C-C, C-N, and C-O bonds in several substrate types using a wide range of nucleophiles high yields enantioselectivities has been identified. Of particular note are the excellent obtained etherification linear cyclic substrates. The potential application Pd-thioether-phosphite systems was also demonstrated by synthesis chiral carbo- heterocycles.
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