作者: Alexandre Baralle , Abdulkader Baroudi , Marion Daniel , Louis Fensterbank , Jean-Philippe Goddard
DOI: 10.1002/9781119953678.RAD023
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摘要: This article deals with the radical chemistry of main-group elements, which has been a particularly active field over last decade. More specifically, we have dealt recent synthetic advances involving nitrogen-, oxygen-, phosphorus-, sulfur-, and selenium-centered radicals. Modes generation these highly reactive entities witnessed tremendous developments their various uses treated exhaustively. Mechanistic scenarios thoroughly discussed, stereoselectivity issues, including asymmetric processes, addressed. Whenever possible, illustrative applications in total synthesis natural products or molecules relevant properties introduced. Keywords: nitrogen; oxygen; phosphorus; sulfur; selenium; radical