Regioselective 6-endo cyclizations of 2-indolylacyl radicals: total synthesis of the pyrido[4,3-b]carbazole alkaloid guatambuine.
作者： M.-Lluïsa Bennasar , Tomàs Roca , Francesc Ferrando
DOI: 10.1021/JO052428S
关键词: Carbazole 、 Olivacine 、 Alkaloid 、 Chemistry 、 Total synthesis 、 Chemical synthesis 、 Regioselectivity 、 Stereochemistry 、 Radical 、 Guatambuine
摘要: A regioselective 6-endo reductive cyclization of 2-indolylacyl radicals constitutes the key step a straightforward synthetic entry to olivacine skeleton, illustrated by total synthesis tetrahydropyridine alkaloid guatambuine.
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