Ion transfer across liquid|liquid interface under forced hydrodynamic conditions. I: Digital simulations
作者： Juan Manuel Ovejero , Ricardo Ariel Fernández , Sergio Alberto Dassie
DOI: 10.1016/J.JELECHEM.2011.11.028
关键词:
摘要: Abstract In this paper, we present the general equations for a model that describes ion transfer reactions across oil|water interface assisted by ligand, under forced hydrodynamic conditions. Our analysis is mainly focused on effect of mechanical stirring aqueous or organic phase during potential sweep, and its influence limiting diffusion currents. The was solved numerically using explicit finite difference; results digital simulations are obtained simple facilitated transfer. corresponding mechanism analyzed in terms current–potential profiles, concentration profiles interfacial distributions, from simulations.
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