Effects of Annealing on the Behavior of Sn in GeSn Alloy and GeSn-Based Photodetectors

作者: Liming Wang , Yichi Zhang , Yifei Wu , Tao Liu , Yuanhao Miao

DOI: 10.1109/TED.2020.3004123

关键词: Annealing (metallurgy)PhotodetectorResponsivityAlloyDark currentMolecular beam epitaxyWaferNanoparticleOptoelectronicsMaterials science

摘要: Ge $_{{1}-{x}}$ Sn x alloy films with contents of 3% and 10% were grown on Si wafers by low-temperature nonequilibrium molecular beam epitaxy. The thermostabilities the GeSn photodetectors containing them studied. No segregation was observed in Ge0.97Sn0.03 annealed below 750 °C. Conversely, occurred nanoparticles formed within Ge0.90Sn0.10 above 400 Upon increasing annealing temperature to °C, particles thermally driven segregated surface both films. Photodetectors fabricated based as-grown Because decreased defect content film after annealing, dark current obviously responsivity devices increased. These results are fundamentally important for applications high-performance lasers alloys.

参考文章(23)
Wenqi Huang, Buwen Cheng, Chunlai Xue, Zhi Liu, Comparative studies of band structures for biaxial (100)-, (110)-, and (111)-strained GeSn: A first-principles calculation with GGA+U approach Journal of Applied Physics. ,vol. 118, pp. 165704- ,(2015) , 10.1063/1.4933394
A. R. Schaefer, E. F. Zalewski, Jon Geist, Silicon detector nonlinearity and related effects. Applied Optics. ,vol. 22, pp. 1232- 1236 ,(1983) , 10.1364/AO.22.001232
Richard Soref, Mid-infrared photonics in silicon and germanium Nature Photonics. ,vol. 4, pp. 495- 497 ,(2010) , 10.1038/NPHOTON.2010.171
V.R. D’Costa, J. Tolle, R. Roucka, C.D. Poweleit, J. Kouvetakis, J. Menéndez, Raman scattering in Ge1−ySny alloys Solid State Communications. ,vol. 144, pp. 240- 244 ,(2007) , 10.1016/J.SSC.2007.08.020
Roman Körner, Wogong Zhang, Erich Kasper, Jörg Schulze, Michael Oehme, Konrad Kostecki, Kaiheng Ye, Stefan Bechler, Kai Ulbricht, Marc Schmid, Mathias Kaschel, Martin Gollhofer, GeSn-on-Si normal incidence photodetectors with bandwidths more than 40 GHz. Optics Express. ,vol. 22, pp. 839- 846 ,(2014) , 10.1364/OE.22.000839
H. Li, Y. X. Cui, K. Y. Wu, W. K. Tseng, H. H. Cheng, H. Chen, Strain relaxation and Sn segregation in GeSn epilayers under thermal treatment Applied Physics Letters. ,vol. 102, pp. 251907- ,(2013) , 10.1063/1.4812490
E. Kasper, M. Kittler, M. Oehme, T. Arguirov, Germanium tin: silicon photonics toward the mid-infrared [Invited] Photonics Research. ,vol. 1, pp. 69- 76 ,(2013) , 10.1364/PRJ.1.000069
Lu Zhang, Yisen Wang, Ningli Chen, Guangyang Lin, Cheng Li, Wei Huang, Songyan Chen, Jianfang Xu, Jianyuan Wang, Raman scattering study of amorphous GeSn films and their crystallization on Si substrates Journal of Non-crystalline Solids. ,vol. 448, pp. 74- 78 ,(2016) , 10.1016/J.JNONCRYSOL.2016.07.007
C. M. Comrie, C. B. Mtshali, P. T. Sechogela, N. M. Santos, K. van Stiphout, R. Loo, W. Vandervorst, A. Vantomme, Interplay between relaxation and Sn segregation during thermal annealing of GeSn strained layers Journal of Applied Physics. ,vol. 120, pp. 145303- ,(2016) , 10.1063/1.4964692
D. Rouchon, V. Reboud, K. Guilloy, J. M. Hartmann, N. Pauc, V. Calvo, A. Gassenq, L. Milord, J. Rothman, J. Aubin, A. Chelnokov, Raman spectral shift versus strain and composition in GeSn layers with 6%–15% Sn content Applied Physics Letters. ,vol. 110, pp. 112101- ,(2017) , 10.1063/1.4978512