The effect of 4,4'-bis(N,N-diethylamino) benzophenone on the degree of conversion in liquid photopolymer for dental 3D printing

作者: Du-Hyeong Lee , Hang Nga Mai , Jin-Chul Yang , Tae-Yub Kwon

DOI: 10.4047/JAP.2015.7.5.386

关键词: Bisphenol ASpectroscopyPolymerizationPhotoinitiatorPhotopolymerBenzophenoneNanotechnologyAnalytical chemistryFourier transform infrared spectroscopyIrradiationMaterials science

摘要: The purpose of this preliminary study was to investigate the effects adding 4,4'-bis(N,N-diethylamino) benzophenone (DEABP) as a co-initiator binary photoinitiating system (camphorquinone-amine) analyze on degree conversion (DC) light-cured resin for dental 3D printing.Cylindrical specimens (N=60, n=30 per group, o5 mm × 1 mm) were fabricated using bisphenol A glycerolate dimethacrylate (BisGMA) both with and without DEABP. freshly mixed resins exposed light in custom-made closed chamber nine light-emitting diode lamps (wavelength: 405 nm; power: 840 mW/cm(2)) polymerization at each incidence light-irradiation 10, 30, 60, 180, 300 seconds, while five time evaluated given irradiation point. Fourier-transform infrared (FTIR) spectroscopy used measure DC values resins. Two-way analysis variance Duncan post hoc test statistically significant differences between groups times (α=.05).In DEABP-containing resin, significantly higher all points (P<.001), also initial velocity faster than DEABP-free resin.The addition DEABP enhanced and, thus, could potentially become an efficient photoinitiator when combined camphorquinone-amine may be utilized more advanced photopolymerization printing.

参考文章(32)
FA Rueggeberg, WF Caughman, Jr Jw Curtis, Effect of light intensity and exposure duration on cure of resin composite. Operative Dentistry. ,vol. 19, pp. 26- 32 ,(1994)
Charles W. Hull, Apparatus for production of three-dimensional objects by stereolithography United States Patent, Appl., No. 638905, Filed. ,(1984)
Kunio IKEMURA, Kensuke ICHIZAWA, Mariko YOSHIDA, So ITO, Takeshi ENDO, UV-VIS spectra and photoinitiation behaviors of acylphosphine oxide and bisacylphosphine oxide derivatives in unfilled, light-cured dental resins. Dental Materials Journal. ,vol. 27, pp. 765- 774 ,(2008) , 10.4012/DMJ.27.765
Pedro Paulo A.C. Albuquerque, Allana D.L. Moreira, Rafael R. Moraes, Larissa M. Cavalcante, Luis Felipe J. Schneider, Color stability, conversion, water sorption and solubility of dental composites formulated with different photoinitiator systems Journal of Dentistry. ,vol. 41, pp. e67- e72 ,(2013) , 10.1016/J.JDENT.2012.11.020
I. Sideridou, V. Tserki, G. Papanastasiou, Effect of chemical structure on degree of conversion in light-cured dimethacrylate-based dental resins Biomaterials. ,vol. 23, pp. 1819- 1829 ,(2002) , 10.1016/S0142-9612(01)00308-8
André Luiz Jardini, Maria Aparecida Larosa, Rubens Maciel Filho, Cecília Amélia de Carvalho Zavaglia, Luis Fernando Bernardes, Carlos Salles Lambert, Davi Reis Calderoni, Paulo Kharmandayan, Cranial reconstruction: 3D biomodel and custom-built implant created using additive manufacturing Journal of Cranio-maxillofacial Surgery. ,vol. 42, pp. 1877- 1884 ,(2014) , 10.1016/J.JCMS.2014.07.006
James V. Crivello, Elsa Reichmanis, Photopolymer Materials and Processes for Advanced Technologies Chemistry of Materials. ,vol. 26, pp. 533- 548 ,(2014) , 10.1021/CM402262G
Yonghua Chen, Chen Zhezheng, Joint analysis in rapid fabrication of non‐assembly mechanisms Rapid Prototyping Journal. ,vol. 17, pp. 408- 417 ,(2011) , 10.1108/13552541111184134
George S. Hammond, Carl C. Wamser, Catherine T. Chang, Charles. Baylor, Photoreaction of Michler's ketone with benzophenone. Triplet exciplex Journal of the American Chemical Society. ,vol. 92, pp. 6362- 6363 ,(1970) , 10.1021/JA00724A058
V. D. McGinniss, T. Provder, C. Kuo, A. Gallopo, Polymerization of Methyl Methacrylate Photoinitiated by 4,4'-Bis(N,N-diethylamino)benzophenone. 1 Macromolecules. ,vol. 11, pp. 393- 404 ,(1978) , 10.1021/MA60062A022