Tribology of silica nanoparticle-reinforced, hydrophobic sol–gel composite coatings

作者: Derrick A. Banerjee , Aaron J. Kessman , Darran R. Cairns , Konstantinos A. Sierros

DOI: 10.1016/J.SURFCOAT.2014.07.091

关键词: Colloidal silicaCoatingAbrasiveComposite materialAbrasion (mechanical)NanoindentationIndentation hardnessMaterials scienceContact angleTribology

摘要: Abstract Hydrophobically functional coatings can be used to protect surfaces and therefore improve the performance lifetime of a broad range applications such as optoelectronics touchscreens. Organic–inorganic hybrid materials silica sol–gel are particularly effective for this purpose, but molecules in these susceptible abrasive wear thus lose their over time harsh environments typically encountered. To combat problems, nanoparticle-reinforced matrix was developed increase hardness resistance overall coating. This study involved analysis fluorinated composite particle reinforced dip-coated on glass substrates. Varying amounts nanoparticles from 0.5 10 wt.% precursor weight were added examine structural dependence mechanisms elucidate strengthening that could lead improvements coating properties. Abrasion conducted using an in-house built reciprocating polishing apparatus. Characterization water contact angle determine hydrophobic functionality after cycles. Atomic force microscopy, lateral nanoindentation, nano-scratch, goniometry, optical microscopy performed at intervals testing characterize degradation It generally found that, among other possible factors, increased indentation led decreased rate. Additionally, optimal amount colloidal 1–2 wt.% precursors provided best mechanical, tribological, performance.

参考文章(23)
Paul Hinz, Helmut Dislich, Anti-reflecting light-scattering coatings via the sol-gel-procedure Journal of Non-crystalline Solids. ,vol. 82, pp. 411- 416 ,(1986) , 10.1016/0022-3093(86)90158-4
A.J. Kessman, S.N. Kukureka, D.R. Cairns, Tribology of non-wetting fluorinated mesoporous silica films Wear. ,vol. 271, pp. 2144- 2149 ,(2011) , 10.1016/J.WEAR.2010.12.066
Maurizio Toselli, Joseph A Gardella, Massimo Messori, Adam M Hawkridge, Francesco Pilati, Claudio Tonelli, Surface chemical analysis of poly(ε‐caprolactone)–perfluoropolyether–poly(ε‐caprolactone) triblock copolymers by X‐ray photoelectron spectroscopy Polymer International. ,vol. 52, pp. 1262- 1274 ,(2003) , 10.1002/PI.1184
C. Schelle, M. Mennig, H. Krug, G. Jonschker, H. Schmidt, One step antiglare sol—gel coating for screens by sol—gel techniques Journal of Non-crystalline Solids. ,vol. 218, pp. 163- 168 ,(1997) , 10.1016/S0022-3093(97)00290-1
Ivan Jerman, Angela Šurca Vuk, Matjaž Koželj, Boris Orel, Brigita Tomšič, Barbara Simončič, Janez Kovač, Aljaž Vilčnik, Structural Properties and Antibacterial Effects of Hydrophobic and Oleophobic Sol-Gel Coatings for Cotton Fabrics Langmuir. ,vol. 25, pp. 5869- 5880 ,(2009) , 10.1021/LA803742C
Frank Samson, Ophthalmic lens coatings Surface & Coatings Technology. ,vol. 81, pp. 79- 86 ,(1996) , 10.1016/0257-8972(95)02532-4
Jin-Hyun Hwang, Burtrand I. Lee, Viktor Klep, Igor Luzinov, Transparent hydrophobic organic–inorganic nanocomposite films Materials Research Bulletin. ,vol. 43, pp. 2652- 2657 ,(2008) , 10.1016/J.MATERRESBULL.2007.10.045
Aaron J. Kessman, Darran R. Cairns, Paul J. Richter, Frank J. Bottari, Mesostructured island formation in sol–gel SiO2 films through controlled, concentration-dependent flocculation of colloidal silica particles Materials Letters. ,vol. 64, pp. 258- 260 ,(2010) , 10.1016/J.MATLET.2009.10.055
Aurélien F. Stalder, Tobias Melchior, Michael Müller, Daniel Sage, Thierry Blu, Michael Unser, Low-bond axisymmetric drop shape analysis for surface tension and contact angle measurements of sessile drops Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 364, pp. 72- 81 ,(2010) , 10.1016/J.COLSURFA.2010.04.040
Hamdy K Elminir, Ahmed E Ghitas, RH Hamid, F El-Hussainy, MM Beheary, Khaled M Abdel-Moneim, None, Effect of dust on the transparent cover of solar collectors Energy Conversion and Management. ,vol. 47, pp. 3192- 3203 ,(2006) , 10.1016/J.ENCONMAN.2006.02.014