Activated carbons from avocado seed: optimisation and application for removal of several emerging organic compounds.

作者: Anderson B Leite , Caroline Saucier , Eder C Lima , Glaydson S Dos Reis , Cibele S Umpierres

DOI: 10.1007/S11356-017-1105-9

关键词: Chemical engineeringRaw materialChemistryPollutantActivated carbonHigh uptakeAdsorptionSorptionPyrolysisContamination

摘要: In this study, avocado seed was successfully used as raw material for producing activated carbons by conventional pyrolysis. order to determine the best condition produce carbons, a 22 full-factorial design of experiment (DOE) with three central points employed varying temperature and time The two evaluated factors (temperature pyrolysis) strongly influenced SBET, pore volumes, hydrophobicity–hydrophilicity ratio (HI) functional groups values; both had negative effect over volumes which means that increasing values leads decrease these responses; on other hand, regards HI, caused positive their values, HI has an enhancement its values. produced carbon exhibited high specific surface areas in range 1122–1584 m2 g−1. Surface characterisation revealed (ASACs) have hydrophilic surfaces predominantly acidic surfaces. prepared ASACs were adsorption 25 emerging organic compounds such 10 pharmaceuticals 15 phenolic presented uptake all pollutants. It observed at higher pyrolysis (700 °C), generated less total sorption capacity uptaking contaminants. Based results work, it is possible conclude can be area very efficient relation treatment polluted waters

参考文章(65)
Matthias Thommes, Katsumi Kaneko, Alexander V. Neimark, James P. Olivier, Francisco Rodriguez-Reinoso, Jean Rouquerol, Kenneth S.W. Sing, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Pure and Applied Chemistry. ,vol. 87, pp. 1051- 1069 ,(2015) , 10.1515/PAC-2014-1117
Basim Abussaud, Hamza A. Asmaly, Ihsanullah, Tawfik A. Saleh, Vinod Kumar Gupta, Tahar laoui, Muataz Ali Atieh, Sorption of phenol from waters on activated carbon impregnated with iron oxide, aluminum oxide and titanium oxide Journal of Molecular Liquids. ,vol. 213, pp. 351- 359 ,(2016) , 10.1016/J.MOLLIQ.2015.08.044
Tatiana Calvete, Eder C Lima, Natali F Cardoso, Silvio LP Dias, Emerson S Ribeiro, None, Removal of Brilliant Green Dye from Aqueous Solutions Using Home Made Activated Carbons Clean-soil Air Water. ,vol. 38, pp. 521- 532 ,(2010) , 10.1002/CLEN.201000027
Karima Ennaciri, Abdelaziz Baçaoui, Michelle Sergent, Abdelrani Yaacoubi, Application of fractional factorial and Doehlert designs for optimizing the preparation of activated carbons from Argan shells Chemometrics and Intelligent Laboratory Systems. ,vol. 139, pp. 48- 57 ,(2014) , 10.1016/J.CHEMOLAB.2014.09.006
Lizie DT Prola, Fernando M Machado, Carlos P Bergmann, Felipe E de Souza, Caline R Gally, Eder C Lima, Matthew A Adebayo, Silvio LP Dias, Tatiana Calvete, None, Adsorption of Direct Blue 53 dye from aqueous solutions by multi-walled carbon nanotubes and activated carbon. Journal of Environmental Management. ,vol. 130, pp. 166- 175 ,(2013) , 10.1016/J.JENVMAN.2013.09.003
Guo Yang, Honglin Chen, Hangdao Qin, Yujun Feng, Amination of activated carbon for enhancing phenol adsorption: Effect of nitrogen-containing functional groups Applied Surface Science. ,vol. 293, pp. 299- 305 ,(2014) , 10.1016/J.APSUSC.2013.12.155
Despo Fatta-Kassinos, Costas Michael, Wastewater reuse applications and contaminants of emerging concern. Environmental Science and Pollution Research. ,vol. 20, pp. 3493- 3495 ,(2013) , 10.1007/S11356-013-1699-5
Alfred Rossner, Shane A. Snyder, Detlef R.U. Knappe, Removal of emerging contaminants of concern by alternative adsorbents. Water Research. ,vol. 43, pp. 3787- 3796 ,(2009) , 10.1016/J.WATRES.2009.06.009
Fernando Barbosa Jr., Francisco J. Krug, Éder C. Lima, Determination of arsenic in sediment and soil slurries by electrothermal atomic absorption spectrometry using W–Rh permanent modifier The Analyst. ,vol. 125, pp. 2079- 2083 ,(2000) , 10.1039/B005783P