Hot-pressed chromium doped zinc sulfide infrared transparent ceramics
作者： Yiyu Li , Yin Liu , Vladimir V. Fedorov , Sergey B. Mirov , Yiquan Wu
DOI: 10.1016/J.SCRIPTAMAT.2016.07.027
关键词: Materials science 、 Transparent ceramics 、 Zinc sulfide 、 Wurtzite crystal structure 、 Mineralogy 、 Chromium 、 Hot pressing 、 Crystallite 、 Microstructure 、 Analytical chemistry 、 Sphalerite
摘要: Abstract The present study, for the first time, reports successful consolidation of chromium doped zinc sulfide (ZnS) polycrystalline infrared (IR) transparent ceramics (maximum transmittance 67% at 11.6 μm) via hot pressing under vacuum. phase composition as-sintered Cr2+:ZnS was determined to be primarily cubic ZnS sphalerite, with a minor amount hexagonal wurtzite. Scanning electron microscopy (SEM) observation sintered showed highly consolidated microstructure. IR absorption and photoluminescence measurements revealed that Cr2+ ions are tetrahedrally coordinated within host lattice.
sci-hub.se 参考文章(37)
Daniel C. Harris, Materials for Infrared Windows and Domes: Properties and Performance ,(1999)
Mohammadreza Nematollahi, Xiaodong Yang, Lars Martin Sandvik Aas, Zahra Ghadyani, Morten Kildemo, Ursula J. Gibson, Turid W. Reenaas, Molecular beam and pulsed laser deposition of ZnS:Cr for intermediate band solar cells Solar Energy Materials and Solar Cells. ,vol. 141, pp. 322- 330 ,(2015) , 10.1016/J.SOLMAT.2015.06.004
Optical properties of 3d-ions in crystals : spectroscopy and crystal field analysis Tsinghua University Press , Springer. ,(2013) , 10.1007/978-3-642-30838-3
Ralph H. Bartram, Brian Henderson, Crystal-Field Engineering of Solid-State Laser Materials ,(2000)
Christophe Chlique, Odile Merdrignac‐Conanec, Noha Hakmeh, Xianghua Zhang, Jean‐Luc Adam, None, Transparent ZnS Ceramics by Sintering of High Purity Monodisperse Nanopowders Journal of the American Ceramic Society. ,vol. 96, pp. 3070- 3074 ,(2013) , 10.1111/JACE.12570
G. Grebe, H.-J. Schulz, Luminescence of Cr2+ Centres and Related Optical Interactions Involving Crystal Field Levels of Chromium Ions in Zinc Sulfide Zeitschrift für Naturforschung A. ,vol. 29, pp. 1803- 1819 ,(1974) , 10.1515/ZNA-1974-1217
S. Ummartyotin, N. Bunnak, J. Juntaro, M. Sain, H. Manuspiya, Synthesis and luminescence properties of ZnS and metal (Mn, Cu)-doped-ZnS ceramic powder Solid State Sciences. ,vol. 14, pp. 299- 304 ,(2012) , 10.1016/J.SOLIDSTATESCIENCES.2011.12.005
Woohong Kim, Colin Baker, Steve Bowman, Catalin Florea, Guillermo Villalobos, Brandon Shaw, Bryan Sadowski, Michael Hunt, Ishwar Aggarwal, Jasbinder Sanghera, Laser oscillation from Ho^3+ doped Lu_2O_3 ceramics Optical Materials Express. ,vol. 3, pp. 913- 919 ,(2013) , 10.1364/OME.3.000913
S.K. Dutta, G.E. Gazza, Transparent Y2O3 by hot-pressing Materials Research Bulletin. ,vol. 4, pp. 791- 796 ,(1969) , 10.1016/0025-5408(69)90001-4
S. B. Mirov, V. V. Fedorov, D. V. Martyshkin, I. S. Moskalev, M. S. Mirov, V. P. Gapontsev, Progress in mid-IR Cr 2+ and Fe 2+ doped II-VI materials and lasers [Invited] Optical Materials Express. ,vol. 1, pp. 898- 910 ,(2011) , 10.1364/OME.1.000898