Wastewater analysis of Census day samples to investigate per capita input of organophosphorus flame retardants and plasticizers into wastewater.
作者： Jake W. O’Brien , Phong K. Thai , Sicco H. Brandsma , Pim E.G. Leonards , Christoph Ort
DOI: 10.1016/J.CHEMOSPHERE.2015.06.014
关键词: Sewage treatment 、 Phosphate 、 Wastewater 、 Environmental chemistry 、 Waste treatment 、 Fire retardant 、 Pollution 、 Plasticizer 、 Gas chromatography 、 Chemistry
摘要: The use of organophosphate esters (PFRs) as flame retardants and plasticizers has increased due to the ban some brominated retardants. There is however concern regarding toxicity, particularly carcinogenicity neurotoxicity, PFRs. In this study we applied wastewater analysis assess PFRs by Australian population. Influent samples were collected from eleven treatment plants (STPs) in Australia on Census day analysed for using gas chromatography coupled with mass spectrometry (GC-MS). Per capita loads calculated accurate head counts. results indicate that tris(2-butoxyethyl) phosphate (TBOEP) highest per input into followed tris(2-chloroisopropyl) (TCIPP), tris(isobutyl) (TIBP), tris(2-chloroethyl) (TCEP) tris(1,3-dichloroisopropyl) (TDCIPP). Similar PFR profiles observed across STPs a comparison European U.S. indicated similar concentrations. We estimate approximately 2.1 mg person−1 day−1 are which equates 16 tonnes annum.
uq.edu.au
core.ac.uk
harvard.edu
cabdirect.org
elsevier.com参考文章(26)
Sandra Brommer, Characterising human exposure to organophosphate ester flame retardants University of Birmingham. ,(2014)
María Pilar Martínez Moral, Métodos analíticos para la determinación de compuestos disruptores endocrinos Universidad de La Rioja. ,(2015)
Bruno Paracchini, Sara Comero, Giovanni Locoro, Barbora Jarošová, Luděk Bláha, Jerker Fick, Oliver Gans, Peter Haglund, Michela Ghiani, Raquel Carvalho, Teresa Lettieri, Stefan Voorspoels, Bernd M. Gawlik, Simona Tavazzi, Robert Loos, David Schwesig, Diana C António, EU Wide Monitoring Survey on Waste Water Treatment Plant Effluents Publications Office of the European Union. ,(2012) , 10.2788/60704
Heather M. Stapleton, Susan Klosterhaus, Sarah Eagle, Jennifer Fuh, John D. Meeker, Arlene Blum, Thomas F. Webster, Detection of organophosphate flame retardants in furniture foam and U.S. house dust. Environmental Science & Technology. ,vol. 43, pp. 7490- 7495 ,(2009) , 10.1021/ES9014019
Thorsten Reemtsma, José Benito Quintana, Rosario Rodil, Mónica Garcı´a-López, Isaac Rodrı´guez, Organophosphorus flame retardants and plasticizers in water and air I. Occurrence and fate Trends in Analytical Chemistry. ,vol. 27, pp. 727- 737 ,(2008) , 10.1016/J.TRAC.2008.07.002
John D. Meeker, Heather M. Stapleton, House Dust Concentrations of Organophosphate Flame Retardants in Relation to Hormone Levels and Semen Quality Parameters Environmental Health Perspectives. ,vol. 118, pp. 318- 323 ,(2009) , 10.1289/EHP.0901332
Anneli Marklund, Barbro Andersson, Peter Haglund, Screening of organophosphorus compounds and their distribution in various indoor environments Chemosphere. ,vol. 53, pp. 1137- 1146 ,(2003) , 10.1016/S0045-6535(03)00666-0
J.A. Andresen, A. Grundmann, K. Bester, Organophosphorus flame retardants and plasticisers in surface waters. Science of The Total Environment. ,vol. 332, pp. 155- 166 ,(2004) , 10.1016/J.SCITOTENV.2004.04.021
Nele Van den Eede, Alin C. Dirtu, Hugo Neels, Adrian Covaci, Analytical developments and preliminary assessment of human exposure to organophosphate flame retardants from indoor dust. Environment International. ,vol. 37, pp. 454- 461 ,(2011) , 10.1016/J.ENVINT.2010.11.010
Jake W. O’Brien, Phong K. Thai, Geoff Eaglesham, Christoph Ort, Andreas Scheidegger, Steve Carter, Foon Yin Lai, Jochen F. Mueller, A model to estimate the population contributing to the wastewater using samples collected on census day Environmental Science & Technology. ,vol. 48, pp. 517- 525 ,(2014) , 10.1021/ES403251G