Structural and mechanical properties of a high-performance BN fibre

作者: S Bernard , F Chassagneux , M.-P Berthet , H Vincent , J Bouix

DOI: 10.1016/S0955-2219(01)00524-6

关键词: Ultimate tensile strengthX-ray crystallographyElastic modulusScanning electron microscopeMineralogyPorosityComposite materialMicrostructureRaman spectroscopyModulusMaterials science

摘要: Abstract The relationship between the structure, microtexture and mechanical properties of a high-performance polyborazine-based BN fibre has been studied in detail. Techniques such as Raman IRTF spectroscopies, X-ray diffraction, scanning transmission electron microscopies microtraction tests were used. It shown that longitudinal directly depend on microtextural structural properties. In particular, Young's modulus fibre-axis ( E =440 GPa) is controlled by structure: presents high degree alignment (002) planes compared with axis τ =0.90) value elastic attributed to strong covalent bonds basal planes. On other hand, ultimate tensile strength σ R =2000 MPa) low density d =1.85 g cm −3 ) are limited external defects porosity volume fibre.

参考文章(12)
K. J. L. Paciorek, R. H. Kratzer, Boron Nitride Preceramic Polymer Studies Proceedings of the 12th Annual Conference on Composites and Advanced Ceramic Materials, Part 1 of 2: Ceramic Engineering and Science Proceedings, Volume 9, Issue 7/8. pp. 993- 999 ,(2008) , 10.1002/9780470310496.CH52
J. Economy, R. V. Anderson, Boron nitride fibers Journal of Polymer Science Part C: Polymer Symposia. ,vol. 19, pp. 283- 297 ,(2007) , 10.1002/POLC.5070190122
Y. Kimura, Y. Kubo, N. Hayashi, High-performance boron-nitride fibers from poly(borazine) preceramics Composites Science and Technology. ,vol. 51, pp. 173- 179 ,(1994) , 10.1016/0266-3538(94)90188-0
Thomas Wideman, Edward E. Remsen, Enriqueta Cortez, Vicki L. Chlanda, Larry G. Sneddon, Amine-Modified Polyborazylenes: Second-Generation Precursors to Boron Nitride Chemistry of Materials. ,vol. 10, pp. 412- 421 ,(1998) , 10.1021/CM970572R
F. A. Miller, C. H. Wilkins, Infrared Spectra and Characteristic Frequencies of Inorganic Ions Analytical Chemistry. ,vol. 24, pp. 1253- 1294 ,(1952) , 10.1021/AC60068A007
R. J. Nemanich, S. A. Solin, Richard M. Martin, Light scattering study of boron nitride microcrystals Physical Review B. ,vol. 23, pp. 6348- 6356 ,(1981) , 10.1103/PHYSREVB.23.6348
Chaitanya K. Narula, Riley Schaeffer, Ahbaya Datye, Robert T. Paine, Synthesis of boron nitride ceramics from 2,4,6-triaminoborazine Inorganic Chemistry. ,vol. 28, pp. 4053- 4055 ,(1989) , 10.1021/IC00320A025
S. N. Patankar, Weibull distribution as applied to ceramic fibres Journal of Materials Science Letters. ,vol. 10, pp. 1176- 1181 ,(1991) , 10.1007/BF00727897
Ralph G. Pearson, PHYSICAL AND INORGANIC CHEMISTRY ,(1963)
Jean Bouix, Philippe Miele, David Cornu, Samuel Bernard, Loïc Rousseau, Christiane Vincent, Jean-Christophe Pasquet, Marie-Paule Berthet, Pascaline Toutois, Bérangère Toury, Procede de fabrication de fibres de nitrure de bore a partir de borylborazines ,(2001)