Effects of LNO buffer layers on electrical properties of BFO-PT thin films on stainless steel substrates

作者: Susu Wang , Hao Wang , Jie Jian , Jianguo Chen , Jinrong Cheng

DOI: 10.1016/J.JALLCOM.2019.01.033

关键词: Thin filmDielectric lossBuffer (optical fiber)FerroelectricityPolarization (electrochemistry)Composite materialCrystallinityDielectricMaterials science

摘要: Abstract Ferroelectric 0.7BiFeO3-0.3PbTiO3 (BFO-PT) thin films were deposited on LaNiO3 (LNO) coated stainless steel (SS) substrates by the sol-gel method. XRD results indicate that both LNO and BFO-PT have perovskite structure film crystallinity is improved with increasing thickness. The dielectric loss of reduced significantly addition buffer layers, achieving about 4% at frequency 1 kHz, much lower than >20% for directly SS substrates. reveal strong ferroelectricity remnant polarization (Pr) 35 μC/cm2 390 nm. Moreover, layers mitigates deterioration after 1.33 × 108 switching cycles resulting in anti-fatigue properties films. Our BFO-PT/LNO multilayer maintain excellent ferroelectric properties.

参考文章(30)
J. YIN, X. Y. CHEN, Q. C. LI, X. Y. LIU, Z. G. LIU, 〈012〉-oriented growth of the films LaNiO3/SiO2/Si(111) by pulsed laser deposition Journal of Materials Science. ,vol. 33, pp. 5631- 5635 ,(1998) , 10.1023/A:1004424517453
Manoj Narayanan, Beihai Ma, U. (Balu) Balachandran, Wei Li, Dielectric spectroscopy of Pb0.92La0.08Zr0.52Ti0.48O3 films on hastelloy substrates with and without LaNiO3 buffer layers Journal of Applied Physics. ,vol. 107, pp. 024103- ,(2010) , 10.1063/1.3291127
Jinrong Cheng, Shengwen Yu, Jianguo Chen, Zhongyan Meng, L. Eric Cross, Dielectric and magnetic enhancements in BiFeO3–PbTiO3 solid solutions with La doping Applied Physics Letters. ,vol. 89, pp. 122911- ,(2006) , 10.1063/1.2353806
W. Jo, D. C. Kim, J. W. Hong, Reverse-poling effects on charge retention in Pb(Zr,Ti)O3(001)/LaNiO3(001) heterostructures Applied Physics Letters. ,vol. 76, pp. 390- 392 ,(2000) , 10.1063/1.125763
Wataru Sakamoto, Asaki Iwata, Toshinobu Yogo, Ferroelectric properties of chemically synthesized perovskite BiFeO3–PbTiO3 thin films Journal of Applied Physics. ,vol. 104, pp. 104106- 104106 ,(2008) , 10.1063/1.3026527
P. Mandal, M. J. Pitcher, J. Alaria, H. Niu, P. Borisov, P. Stamenov, J. B. Claridge, M. J. Rosseinsky, Designing switchable polarization and magnetization at room temperature in an oxide Nature. ,vol. 525, pp. 363- 366 ,(2015) , 10.1038/NATURE14881
Jie Wang, X. G. Tang, H. L. W. Chan, C. L. Choy, Haosu Luo, Dielectric relaxation and electrical properties of 0.94Pb(Fe1∕2Nb1∕2)O3–0.06PbTiO3 single crystals Applied Physics Letters. ,vol. 86, pp. 152907- ,(2005) , 10.1063/1.1901818
A. Yu. Dobin, K. R. Nikolaev, I. N. Krivorotov, R. M. Wentzcovitch, E. Dan Dahlberg, A. M. Goldman, Electronic and crystal structure of fully strainedLaNiO3films Physical Review B. ,vol. 68, pp. 113408- ,(2003) , 10.1103/PHYSREVB.68.113408
Haimin Li, Jianguo Zhu, Jia Zhuang, Yu Hu, Mingzhe Huai, Qingsong Yang, Enhanced ferroelectric and dielectric properties of BiFeO3–PbTiO3 thin films grown via a sol–gel multilayer deposition method Journal of Sol-Gel Science and Technology. ,vol. 75, pp. 353- 359 ,(2015) , 10.1007/S10971-015-3706-4
Ruguan Li, Shuwen Jiang, Libin Gao, Yanrong Li, Enhanced leakage current performance and conduction mechanisms of Bi1.5Zn1.0Nb1.5O7/Ba0.5Sr0.5TiO3 bilayered thin films Journal of Applied Physics. ,vol. 112, pp. 074113- ,(2012) , 10.1063/1.4757952