Perfluoroalkylated diblock-alkyl methacrylate monomers for biomedical applications: Wettability of their copolymers with HEMA and DEGMA
作者： Robert Kaplánek , Oldřich Paleta , Jiří Michálek , Martin Přádný
DOI: 10.1016/J.JFLUCHEM.2005.01.004
关键词: Methacryloyl chloride 、 Acylation 、 Copolymer 、 Organic chemistry 、 Polymer chemistry 、 Alkyl methacrylate 、 Wetting 、 Swelling 、 Monomer 、 Chemistry
摘要: Abstract The intermediate perfluoroalkylated diblock hydrophobic–hydrophilic secondary alcohols (9–11), which were prepared by the reaction of monomethyl ethers oligomeric ethyleneglycols with 2-[(perfluoroalkyl)methyl]oxiranes (7 and 8), resulted in formation title monomers (12–14) acylation methacryloyl chloride. Copolymers 12–14 HEMA DEGMA under radical conditions display enhanced swelling properties.
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