Site-selective spectroscopy of Ho3+ ions in CsCdBr3 crystals.

作者: Marjorie Mujaji , G. D. Jones , R. W. G. Syme

DOI: 10.1103/PHYSREVB.48.710

关键词: ExcitationInorganic compoundFluorescenceIonHolmiumOpticsMaterials scienceSpectroscopyAtomic physicsPhoton upconversionPhotoluminescence

摘要: With the use of laser-selective excitation, an extensive set energy levels has been established for principal Ho 3+ dimer center in CsCdBr 3 :Ho crystals. The observed splittings around 2 cm -1 transitions to or from assigned as having γ symmetry under C 3υ is indicative deviations ion-site exact symmetry. As previously studied Er pair , exhibits strong upconversion fluorescence with up one-third intensity direct cw laser excitation 5 I 8 → S transition green and one-fifteenth comparable F red

参考文章(25)
Gary L. McPherson, Arlene M. McPherson, Jerry L. Atwood, Structures of CsMgBr3, CsCdBr3 and CsMgI3— diamagnetic linear chain lattices Journal of Physics and Chemistry of Solids. ,vol. 41, pp. 495- 499 ,(1980) , 10.1016/0022-3697(80)90180-8
Larry M. Henling, Gary L. McPherson, EPR spectra of magnetically coupled pairs of Gd 3+ ions in crystals of CsMgCl 3 , CsMgBr 3 , and CsCdBr 3 Physical Review B. ,vol. 16, pp. 4756- 4760 ,(1977) , 10.1103/PHYSREVB.16.4756
Gary L. McPherson, Larry M. Henling, EPR spectrum of coupled pairs ofGd3+ions in single crystals of CsCdBr3 Physical Review B. ,vol. 16, pp. 1889- 1892 ,(1977) , 10.1103/PHYSREVB.16.1889
G. Blasse, A. Wolfert, G.L. McPherson, Low-temperature Ce3+ luminescence in CsCdBr3 crystals Journal of Solid State Chemistry. ,vol. 57, pp. 396- 398 ,(1985) , 10.1016/0022-4596(85)90205-1
J.P. Chaminade, R.M. Macfarlane, F. Ramaz, J.C. Vial, High resolution laser spectroscopy of rare earth doped CsCdBr3 Journal of Luminescence. pp. 531- 535 ,(1991) , 10.1016/0022-2313(91)90186-Y
F. Ramaz, J.C. Vial, R.M. Macfarlane, Measurement of the Nd3+ ion pair interaction and Zeeman effect in CsCdBr3:Nd3+ using spectral holeburning Journal of Luminescence. ,vol. 53, pp. 244- 246 ,(1992) , 10.1016/0022-2313(92)90147-2
R. B. Barthem, R. Buisson, R. L. Cone, Spectroscopic analysis of Nd3+ pairs in CsCdBr3 Journal of Chemical Physics. ,vol. 91, pp. 627- 632 ,(1989) , 10.1063/1.457167
R.B. Barthem, R. Buisson, F. Madèore, J.C. Vial, J.P. Chaminade, De-excitation processes of optically excited Nd3+ pairs in CsCdBr3 Journal De Physique. ,vol. 48, pp. 379- 387 ,(1987) , 10.1051/JPHYS:01987004803037900
C. Barthou, R.B. Barthem, Strongly coupled Nd3+ ion pairs in CsCdBr3: Optical properties and energy transfer Journal of Luminescence. ,vol. 46, pp. 9- 15 ,(1990) , 10.1016/0022-2313(90)90076-N
P. A. M. Berdowski, M. J. J. Lammers, G. Blasse, 5D3–5D4 cross relaxation in Tb3+ pairs in CsCdBr3 crystals Journal of Chemical Physics. ,vol. 83, pp. 476- 479 ,(1985) , 10.1063/1.449562