Graphene oxide mediated thiolation of indoles in water: a green and sustainable approach to synthesize 3-sulfenylindoles
作者： Min Chen , Yi Luo , Chen Zhang , Li Guo , Qiantao Wang
DOI: 10.1039/C8QO00726H
关键词: Combinatorial chemistry 、 Substrate (chemistry) 、 Oxide 、 Graphene 、 Functional group 、 Iodine.free 、 Reagent 、 Chemistry
摘要: An atom economical and transition-metal iodine free procedure of graphene oxide (a heterogeneous, recyclable, inexpensive, environment-friendly carbocatalyst) mediated thiolation indoles, using thiols as a thiolating reagent, has been developed. This methodology provides catalyst-recyclable organic-solvent-free protocol to afford 3-sulfenylindoles with good functional group tolerance broad substrate scope.
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