Lewis acidic borane adducts of pyridines and stilbazoles for nonlinear optics
作者： MJ Gerald Lesley , Alden Woodward , Nicholas J Taylor , Todd B Marder , Iréne Cazenobe
DOI: 10.1021/CM9707519
关键词: Pyridine 、 Lewis acids and bases 、 Borane 、 Orthorhombic crystal system 、 Dipole 、 Adduct 、 Nonlinear optics 、 Crystallography 、 Chemistry 、 Stereochemistry 、 Luminescence
摘要: A series of neutral pyridyl adducts involving the strong Lewis acids BF3 and B(C6F5)3 has been prepared, their second-order nonlinear optical coefficients (EFISH method) have examined. The formation pyridyl−boron bond leads to enhancement dipole moments NLO (β β(0)). Reactions DMAP (4-Me2N−C5H4N) with BH3, BF3, give corresponding pyridine DMAP·BH3 (orthorhombic, Pbca, a = 9.6914(7) A; b 11.7173(9) c 22.718(2) V 1622.4(5) A3; Z 8; p 1.114 g cm-3), DMAP·BF3 10.430(3) 8.111(2) 20.295(7) 1717.0(9) 1.470 DMAP·B(C6F5)3 12.322(1) 20.556(2) 28.455(3) 7207.4(14) 1.508 cm-3). Me2N−4-C6H4−CHCH−C5H4N, MeO−4-C6H4−CHCH−C5H4N, Me2N−4-C6H4−C⋮C−C5H4N result in materials that are highly luminescent incorporate structural features ...
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sci-hub.se 参考文章(40)
Paul Nguyen, Gerry Lesley, Chaoyang Dai, Nicholas J. Taylor, Todd B. Marder, Vano Chu, Christopher Viney, Isabelle Ledoux, Joseph Zyss, Well-Defined Conjugated Rigid-Rods as Multifunctional Materials: Linear and Nonlinear Optical Properties and Liquid Crystalline Behavior Springer Netherlands. pp. 333- 347 ,(1995) , 10.1007/978-94-011-0337-4_19
A.G. Massey, A.J. Park, Perfluorophenyl derivatives of the elements : I. Tris(pentafluorophenyl)boron Journal of Organometallic Chemistry. ,vol. 2, pp. 245- 250 ,(1964) , 10.1016/S0022-328X(00)80518-5
Lap Tak Cheng, Wilson Tam, Sylvia H. Stevenson, Gerald R. Meredith, Geert Rikken, Seth R. Marder, Experimental investigations of organic molecular nonlinear optical polarizabilities. 1. Methods and results on benzene and stilbene derivatives The Journal of Physical Chemistry. ,vol. 95, pp. 10631- 10643 ,(1991) , 10.1021/J100179A026
L-T. Cheng, W. Tam, G. R. Meredith, S. R. Marder, Quadratic hyperpolarizabilities of some organometallic compounds Molecular Crystals and Liquid Crystals. ,vol. 189, pp. 137- 153 ,(1990) , 10.1080/00268949008037228
Hisao Tabei, Takashi Kurihara, Toshikuni Kaino, Recrystallization solvent effects on second‐order nonlinear optical organic materials Applied Physics Letters. ,vol. 50, pp. 1855- 1857 ,(1987) , 10.1063/1.97716
David R. Kanis, Pascal G. Lacroix, Mark A. Ratner, Tobin J. Marks, Electronic Structure and Quadratic Hyperpolarizabilities in Organotransition-Metal Chromophores Having Weakly Coupled .pi.-Networks. Unusual Mechanisms for Second-Order Response Journal of the American Chemical Society. ,vol. 116, pp. 10089- 10102 ,(1994) , 10.1021/JA00101A030
Duncan W. Bruce, Martin Grayson, Ronan Le Lagadec, Barry T. Pickup, Anna Thornton, Robert G. Denning, Kai K. Lai, Macroscopic non‐linearities of some stilbazolium derivatives and the calculatium derivatives and the calculation of their molecular hyperpolarisability Advanced Materials for Optics and Electronics. ,vol. 4, pp. 293- 301 ,(1994) , 10.1002/AMO.860040409
M. Bourgault, C. Mountassir, H. Le Bozec, I. Ledoux, G. Pucetti, J. Zyss, Synthesis and second-order nonlinear optical properties of new bipyridyl metal complexes Journal of the Chemical Society, Chemical Communications. pp. 1623- 1624 ,(1993) , 10.1039/C39930001623
Takashi Kurihara, Hisao Tabei, Toshikuni Kaino, A new organic material exhibiting highly efficient phase-matched second harmonic generation: 4-methoxy-4′-nitrotolan Journal of The Chemical Society, Chemical Communications. pp. 959- 960 ,(1987) , 10.1039/C39870000959
J. Zyss, D. S. Chemla, J. F. Nicoud, Demonstration of efficient nonlinear optical crystals with vanishing molecular dipole moment: Second‐harmonic generation in 3‐methyl‐4‐nitropyridine‐1‐oxide Journal of Chemical Physics. ,vol. 74, pp. 4800- 4811 ,(1981) , 10.1063/1.441759