Spreading of trisiloxanes over thin aqueous layers
作者： K. S. Lee , V. M. Starov , T. J. P. Muchatuta , S. I. R. Srikantha
DOI: 10.1134/S1061933X09030119
关键词: Wetting 、 Marangoni force 、 Marangoni effect 、 Ethylene glycol 、 Chemical physics 、 Silicone 、 Chemistry 、 Surface tension gradient 、 Polymer chemistry 、 Aqueous solution
摘要: Surfactants are widely spread in nature and increasingly used industry as wetting, cleaning disinfecting agents. Recently, there newly discovered trisiloxanes other silicone based surfactants which show very unusual spreading behaviour. Although a number of experimental theoretical investigations have been carried out, the underlying mechanism remains unclear. Experiments using comparison with 3 different poly(ethylene glycol) monododecyl ethers (C12E4, C12E5, C12E6) were performed to understand influence Marangoni force driving for spreading. We then compared our results available predictions literature. The obtained data showed opposite trend developed regular surfactants. latter is assumed be special feature “superspreaders”.
springer.com
lboro.ac.uk
sci-hub.se 参考文章(9)
Victor M. Starov, Alain de Ryck, Manuel G. Velarde, On the Spreading of an Insoluble Surfactant over a Thin Viscous Liquid Layer Journal of Colloid and Interface Science. ,vol. 190, pp. 104- 113 ,(1997) , 10.1006/JCIS.1997.4863
K.S. Lee, V.M. Starov, Spreading of surfactant solutions over thin aqueous layers: influence of solubility and micelles disintegration. Journal of Colloid and Interface Science. ,vol. 314, pp. 631- 642 ,(2007) , 10.1016/J.JCIS.2007.06.009
T. Stoebe, Zuxuan Lin, Randal M. Hill, Michael D. Ward, H. Ted Davis, Enhanced Spreading of Aqueous Films Containing Ethoxylated Alcohol Surfactants on Solid Substrates Langmuir. ,vol. 13, pp. 7270- 7275 ,(1997) , 10.1021/LA970702A
S. Zhu, W.G. Miller, L.E. Scriven, H.T. Davis, Superspreading of water—silicone surfactant on hydrophobic surfaces Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 90, pp. 63- 78 ,(1994) , 10.1016/0927-7757(94)02904-0
T. Stoebe, Zuxuan Lin, Randal M. Hill, Michael D. Ward, H. Ted Davis, Surfactant-enhanced spreading Langmuir. ,vol. 12, pp. 337- 344 ,(1996) , 10.1021/LA950513X
Timothy P. Stevens, Robert A. Sinkin, Surfactant replacement therapy. Chest. ,vol. 131, pp. 1577- 1582 ,(2007) , 10.1378/CHEST.06-2371
Alex D Nikolov, Darsh T Wasan, Anoop Chengara, Kalman Koczo, George A Policello, Istvan Kolossvary, Superspreading driven by Marangoni flow Advances in Colloid and Interface Science. ,vol. 96, pp. 325- 338 ,(2002) , 10.1016/S0001-8686(01)00087-2
H. P. Le, Progress and trends in ink-jet printing technology Journal of Imaging Science and Technology. ,vol. 42, pp. 49- 62 ,(1998)
R. M. Hill, Superspreading : Thermodynamic and theoretical aspects Current Opinion in Colloid and Interface Science. ,vol. 3, pp. 247- 254 ,(1998)